phenyl (2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Base Information

Chemical Name:phenyl (2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside
CAS No.:204199-44-0
Molecular Formula:C₃₂H₃₅N₃O₉S
Molecular Weight:637.711
Hs Code.:

Synonyms:phenyl (2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Suppliers and Price of phenyl (2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl (2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl (2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

There total 7 articles about phenyl (2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 204199-43-9
phenyl (3,4,6-tri-O-acetyl-2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

: 204199-44-0
phenyl (2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Guidance literature:: With tetrafluoroboric acid diethyl ether; In methanol; at 23 ℃; for 72h;
DOI:10.1002/(sici)1521-3773(19980202)37:1/2<138::aid-anie138>3.0.co;2-t

Reference yield:

: 204199-42-8
phenyl 2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

: 204199-44-0
phenyl (2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 63.5 percent / 2,6-di-tert-butyl-4-methylpyridine; 4-Angstroem molecular sieves; silver trifluoromethanesulfonate / CH₂Cl₂ / 2 h / -20 - 0 °C

2: 79 percent / HBF₄ / methanol; diethyl ether / 72 h / 23 °C

With tetrafluoroboric acid; 2,6-di-tert-butyl-4-methylpyridine; 4 A molecular sieve; silver trifluoromethanesulfonate; In methanol; diethyl ether; dichloromethane; 1: Condensation / 2: Deacetylation;
DOI:10.1021/jo980660a

Reference yield:

: 67817-16-7
3,4,6-tri-O-acetyl-2-azido-2-deoxy-β-D-glucopyranosyl chloride

: 204199-44-0
phenyl (2-azido-2-deoxy-α-D-glucopyranosyl)-(1->3)-2-O-benzoyl-4-O-benzyl-1-thio-α-L-rhamnopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 64 percent / 2,6-di-tert-butyl-4-methylpyridine, CF₃SO₂OAg / CH₂Cl₂ / 2 h / 0 °C

2: 79 percent / HBF₄*Et₂O / methanol / 72 h / 23 °C

With tetrafluoroboric acid diethyl ether; 2,6-di-tert-butyl-4-methylpyridine; silver trifluoromethanesulfonate; In methanol; dichloromethane;
DOI:10.1002/(sici)1521-3773(19980202)37:1/2<138::aid-anie138>3.0.co;2-t