Cp*Re(CO)(H)(p-N₂C₆H₄OCH₃)

Base Information

Chemical Name:Cp*Re(CO)(H)(p-N₂C₆H₄OCH₃)
CAS No.:94405-83-1
Molecular Formula:C₁₈H₂₃N₂O₂Re
Molecular Weight:485.6
Hs Code.:

Cp*Re(CO)(H)(p-N<sub>2</sub>C<sub>6</sub>H<sub>4</sub>OCH<sub>3</sub>)

Synonyms:Cp*Re(CO)(H)(p-N₂C₆H₄OCH₃)

Suppliers and Price of Cp*Re(CO)(H)(p-N₂C₆H₄OCH₃)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Cp*Re(CO)(H)(p-N₂C₆H₄OCH₃)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Cp*Re(CO)(H)(p-N₂C₆H₄OCH₃)

There total 6 articles about Cp*Re(CO)(H)(p-N₂C₆H₄OCH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 92786-90-8
{Cp*Re(CO)2(p-N₂C₆H₄OMe)}{BF₄}

: 94405-83-1
Cp*Re(CO)(H)(p-N₂C₆H₄OCH₃)

Guidance literature:: With NaOH or KOH; In dichloromethane; water; (N2), complex dissolved in CH2Cl2, aq. 6 M NaOH added while vigorously stirring; solvent removed by pumping (room temp.), dissolved in THF, filtered through Celite, THF pumped off, extd. into hexane, chromd. on neutral alumina, eluted with C6H6, C6H6 pumped off, dissolved in pentane, pptd. during 6 h at -78°C, elem. anal.;

Reference yield: 44.0%

: 92786-90-8
{Cp*Re(CO)2(p-N₂C₆H₄OMe)}{BF₄}

: 92787-15-0
(η(5)-pentamethylcyclopentadienyl)Re(CO)2(N2)

: 94405-83-1
Cp*Re(CO)(H)(p-N₂C₆H₄OCH₃)

Guidance literature:: With NaBH₄; In not given; an excess of NaBH4 was added to a soln. of complex in acetone or acetonitrile; the mixt. was stirred for 1 h at room temp. (N2); hexane was added, chromd. on a silica gel column, eluent hexane; recrystd. from hexane-pentane at -20°C; elem. anal.;

Reference yield:

: 16940-66-2
sodium tetrahydroborate

: 101835-38-5
{Cp*Re(CO)(PMe₃)(p-N₂C₆H₄OMe)}{BF₄}

: 94405-83-1
Cp*Re(CO)(H)(p-N₂C₆H₄OCH₃)

Guidance literature:: In acetone; under N2, addn. of excess solid NaBH4, stirred (1 h, room temp.), color change orange-red to yellow; evapn., extn. (hexane);