Technology Process of C22H30O4
There total 13 articles about C22H30O4 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
methyllithium;
With
cerium(III) chloride bis(lithium chloride);
In
tetrahydrofuran;
at -78 ℃;
for 2.5h;
Inert atmosphere;
C21H26O4;
With
cerium(III) chloride bis(lithium chloride);
In
tetrahydrofuran;
at -78 ℃;
for 0.0833333h;
Inert atmosphere;
DOI:10.1021/ol3007259
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: perchloric acid / dichloromethane / 0.17 h / 0 °C / Sonication
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.25 h / -78 °C / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere
3.1: boron trifluoride diethyl etherate / tetrahydrofuran / 12 h / 20 °C / Inert atmosphere
4.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / 12 h / 20 °C / Inert atmosphere
5.1: cerium(III) chloride bis(lithium chloride) / tetrahydrofuran / 2.5 h / -78 °C / Inert atmosphere
5.2: 0.08 h / -78 °C / Inert atmosphere
With
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; perchloric acid; oxalyl dichloride; cerium(III) chloride bis(lithium chloride); boron trifluoride diethyl etherate; dimethyl sulfoxide;
In
tetrahydrofuran; dichloromethane;
2.1: Swern oxidation / 2.2: Swern oxidation;
DOI:10.1021/ol3007259
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: boron trifluoride diethyl etherate / tetrahydrofuran / 12 h / 20 °C / Inert atmosphere
2.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / 12 h / 20 °C / Inert atmosphere
3.1: cerium(III) chloride bis(lithium chloride) / tetrahydrofuran / 2.5 h / -78 °C / Inert atmosphere
3.2: 0.08 h / -78 °C / Inert atmosphere
With
tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; cerium(III) chloride bis(lithium chloride); boron trifluoride diethyl etherate;
In
tetrahydrofuran;
DOI:10.1021/ol3007259
