1-[4-trifluoromethylphenyl(dimethyl)]silyl-2-phenyl-3,5-bis(trimethylsilyl)benzene

Base Information

Chemical Name:1-[4-trifluoromethylphenyl(dimethyl)]silyl-2-phenyl-3,5-bis(trimethylsilyl)benzene
CAS No.:1438770-12-7
Molecular Formula:C₂₇H₃₅F₃Si₃
Molecular Weight:500.827
Hs Code.:

Synonyms:1-[4-trifluoromethylphenyl(dimethyl)]silyl-2-phenyl-3,5-bis(trimethylsilyl)benzene

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Chemical Property of 1-[4-trifluoromethylphenyl(dimethyl)]silyl-2-phenyl-3,5-bis(trimethylsilyl)benzene

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Technology Process of 1-[4-trifluoromethylphenyl(dimethyl)]silyl-2-phenyl-3,5-bis(trimethylsilyl)benzene

There total 3 articles about 1-[4-trifluoromethylphenyl(dimethyl)]silyl-2-phenyl-3,5-bis(trimethylsilyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1438769-26-6
(E)-1-iodo-1-dimethyl(4-trifluoromethylphenyl)silyl-2-phenylethene

: 1066-54-2
trimethylsilylacetylene

: 1438770-12-7
1-[4-trifluoromethylphenyl(dimethyl)]silyl-2-phenyl-3,5-bis(trimethylsilyl)benzene

Guidance literature:: With palladium diacetate; N-ethyl-N,N-diisopropylamine; at 30 ℃; for 24h;
DOI:10.1021/ol4010883

Reference yield:

: 60457-98-9
chlorodimethyl[4-(trifluoromethyl)phenyl]silane

: 1438770-12-7
1-[4-trifluoromethylphenyl(dimethyl)]silyl-2-phenyl-3,5-bis(trimethylsilyl)benzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / -78 - 0 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: diisobutylaluminium hydride / hexane; tetrahydrofuran / 0 - 50 °C / Inert atmosphere

2.2: 3 h / 0 - 20 °C / Inert atmosphere

3.1: palladium diacetate; N-ethyl-N,N-diisopropylamine / 24 h / 30 °C

With n-butyllithium; palladium diacetate; diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; hexane;
DOI:10.1021/ol4010883

Reference yield:

: dimethyl(phenylethynyl)(4-trifluoromethyl-phenyl)silane

: 1438770-12-7
1-[4-trifluoromethylphenyl(dimethyl)]silyl-2-phenyl-3,5-bis(trimethylsilyl)benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: diisobutylaluminium hydride / hexane; tetrahydrofuran / 0 - 50 °C / Inert atmosphere

1.2: 3 h / 0 - 20 °C / Inert atmosphere

2.1: palladium diacetate; N-ethyl-N,N-diisopropylamine / 24 h / 30 °C

With palladium diacetate; diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; hexane;
DOI:10.1021/ol4010883