cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II)

Base Information

Chemical Name:cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II)
CAS No.:105373-23-7
Molecular Formula:C₃₅H₆₀P₂Pt
Molecular Weight:737.889
Hs Code.:

Synonyms:cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II)

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Chemical Property of cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II)

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Technology Process of cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II)

There total 3 articles about cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: cis-[bis-(dicyclohexylphosphino)ethane]hydridoneopentylplatinum(II)

: 108-67-8
1,3,5-trimethyl-benzene

: 105373-24-8
cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II)

: 105373-23-7
cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II)

Guidance literature:: In 1,2,5-trimethyl-benzene; thermolysis of cis-hydridoneopentyl{bis(dicyclohexylphosphino)ethane}platinum(II) in mesitylene via supposed {bis(dicyclohexylphosphino)ethane}platinum(0) at 69°C for 4.2 h , equilibrating after about 40 h heating; Kinetics;
DOI:10.1021/ja00213a016

Reference yield: 15.0%

: 67407-57-2
cis-chloro(2,4,6-trimethylphenyl)(1,5-cyclooctadiene)platinum(II)

: 23743-26-2
1,2-bis-(dicyclohexylphosphino)ethane

: 105373-23-7
cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II)

Guidance literature:: With Na{HB(OMe)3}; In dichloromethane; bis(dicyclohexylphosphino)ethane to cis-chloro(2,4,6-trimethylphenyl)(1,5-cyclooctadiene)Pt(II) in CH2Cl2,stirred overnight,solvent evapn.,residual oil/gummy solid treated with Na{HB(OMe)3} in THF,cloudy soln. stirred 3 days,quenched by H2O(0°C); aq.layer extd. with CH2Cl2, evapd., dissolved in minimum THF, 1 part MeOH added, crystn. at -10°C;
DOI:10.1021/ja00213a016

Reference yield:

: cis-{bis(dicyclohexylphosphino)ethane}chloroneopentylplatinum(II)

: 105373-24-8
cis-hydrido(3,5-dimethylbenzyl){bis(dicyclohexylphosphino)ethane}platinum(II)

: 105373-23-7
cis-hydrido(2,4,6-trimethylphenyl){bis(dicyclohexylphosphino)ethane}platinum(II)

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran

2: 1,3,5-trimethyl-benzene

In tetrahydrofuran; 1,3,5-trimethyl-benzene;
DOI:10.1021/ja00285a039