Methyl 5-O-(tert-butyldiphenylsilyl)-3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside

Base Information

Chemical Name:Methyl 5-O-(tert-butyldiphenylsilyl)-3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside
CAS No.:161606-78-6
Molecular Formula:C₃₀H₃₈O₄Si
Molecular Weight:490.715
Hs Code.:

Synonyms:Methyl 5-O-(tert-butyldiphenylsilyl)-3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside

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Chemical Property of Methyl 5-O-(tert-butyldiphenylsilyl)-3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside

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Technology Process of Methyl 5-O-(tert-butyldiphenylsilyl)-3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside

There total 3 articles about Methyl 5-O-(tert-butyldiphenylsilyl)-3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 161606-72-0
Methyl 3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside

: 161606-78-6
Methyl 5-O-(tert-butyldiphenylsilyl)-3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside

Guidance literature:: With pyridine; 1H-imidazole; at 20 ℃; for 17h;
DOI:10.1021/jo00106a035

Reference yield:

: 105454-48-6
3-O-Benzyl-2-deoxy-5-(triphenylmethyl)-D-erythro-pentofuranoside

: 161606-78-6
Methyl 5-O-(tert-butyldiphenylsilyl)-3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside

Guidance literature:: Multi-step reaction with 4 steps

1: methanolic HCl / 3.5 h / 20 °C

2: 1.) (COCl)2, DMSO, 2.) NEt₃ / 1.) CH₂Cl₂, ca. -50 deg C, 15 min, 2.) ca. -50 deg C to 20 deg C

3: diethyl ether / -70 °C

4: 99 percent / pyridine, imidazole / 17 h / 20 °C

With pyridine; 1H-imidazole; hydrogenchloride; oxalyl dichloride; dimethyl sulfoxide; triethylamine; In diethyl ether;
DOI:10.1021/jo00106a035

Reference yield:

: 161661-39-8
Methyl 3-O-benzyl-2-deoxy-5-β-D-erythro-pentodialdo-1,4-furanoside

: 161606-78-6
Methyl 5-O-(tert-butyldiphenylsilyl)-3-O-benzyl-2,6-dideoxy-β-D-ribo-hexofuranoside

Guidance literature:: Multi-step reaction with 2 steps

1: diethyl ether / -70 °C

2: 99 percent / pyridine, imidazole / 17 h / 20 °C

With pyridine; 1H-imidazole; In diethyl ether;
DOI:10.1021/jo00106a035