3-[8-benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester

Base Information

Chemical Name:3-[8-benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester
CAS No.:924282-31-5
Molecular Formula:C₃₆H₅₂O₇Si
Molecular Weight:624.89
Hs Code.:

3-[8-benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-<i>b</i>]pyran-2-yl]-acrylic acid methyl ester

Synonyms:3-[8-benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester

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Chemical Property of 3-[8-benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester

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Technology Process of 3-[8-benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester

There total 1 articles about 3-[8-benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 79271-56-0
triethylsilyl trifluoromethyl sulfonate

: 169895-52-7
(E)-3-[(2R,3S,4aR,6R,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-3-hydroxy-2-methyl-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester

: 924282-31-5
3-[8-benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃;
DOI:10.1016/j.tetlet.2006.11.058

Reference yield:

: 924282-31-5
3-[8-benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester

: 924282-40-6
3-[3-hydroxy-2-methyl-8-triisopropylsilanyloxy-6-(3-triisopropylsilanyloxy-propyl)-octahydro-pyrano[3,2-b]pyran-2-yl]-propionic acid 2-(tert-butyl-dimethyl-silanyloxy)-2-methyl-1-[3-(2,4,6-trichloro-benzyloxy)-propyl]-but-3-enyl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: hydrogen / Pd(OH)2-C / ethyl acetate / 20 °C

2.1: 2,6-lutidine / dimethylformamide / 20 - 70 °C

3.1: LiAlH₄ / diethyl ether / 0 °C

4.1: SO₃*pyridine; DMSO; Et₃N / CH₂Cl₂ / 0 °C

4.2: NaClO₂; 2-methyl-2-butene; aq. NaH₂PO₄ / tetrahydrofuran / 0 °C

5.1: 2,4,5-trichlorobenzoyl chloride; Et₃N / tetrahydrofuran / 20 °C

5.2: 81 percent / DMAP / tetrahydrofuran; toluene / 20 °C

6.1: 94 percent / CSA / methanol / 0 °C

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; pyridine-SO₃ complex; camphor-10-sulfonic acid; hydrogen; dimethyl sulfoxide; triethylamine; 2,4,6-trichlorobenzoyl chloride; palladium hydroxide - carbon; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 5.1: Yamaguchi reaction;
DOI:10.1016/j.tetlet.2006.11.058

Reference yield:

: 924282-31-5
3-[8-benzyloxy-6-(3-benzyloxy-propyl)-2-methyl-3-triethylsilanyloxy-octahydro-pyrano[3,2-b]pyran-2-yl]-acrylic acid methyl ester

: 924282-43-9
8-{2-(tert-butyl-dimethyl-silanyloxy)-2-methyl-1-[3-(2,4,6-trichloro-benzyloxy)-propyl]-but-3-enyloxy}-5a-methyl-4-triisopropylsilanyloxy-2-(3-triisopropylsilanyloxy-propyl)-9-vinyl-dodecahydro-1,5,10-trioxa-cyclohepta[b]naphthalene

Guidance literature:: Multi-step reaction with 7 steps

1.1: hydrogen / Pd(OH)2-C / ethyl acetate / 20 °C

2.1: 2,6-lutidine / dimethylformamide / 20 - 70 °C

3.1: LiAlH₄ / diethyl ether / 0 °C

4.1: SO₃*pyridine; DMSO; Et₃N / CH₂Cl₂ / 0 °C

4.2: NaClO₂; 2-methyl-2-butene; aq. NaH₂PO₄ / tetrahydrofuran / 0 °C

5.1: 2,4,5-trichlorobenzoyl chloride; Et₃N / tetrahydrofuran / 20 °C

5.2: 81 percent / DMAP / tetrahydrofuran; toluene / 20 °C

6.1: 94 percent / CSA / methanol / 0 °C

With 2,6-dimethylpyridine; lithium aluminium tetrahydride; pyridine-SO₃ complex; camphor-10-sulfonic acid; hydrogen; dimethyl sulfoxide; triethylamine; 2,4,6-trichlorobenzoyl chloride; palladium hydroxide - carbon; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 5.1: Yamaguchi reaction;
DOI:10.1016/j.tetlet.2006.11.058