2-(2-hydroxy-5-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline

Base Information

• Chemical Name: 2-(2-hydroxy-5-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline
• CAS No.: 1420904-53-5
• Molecular Formula: C₁₉H₁₁BrN₄O
• Molecular Weight: 391.227
• Mol file: 1420904-53-5.mol

Synonyms:2-(2-hydroxy-5-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline

Chemical Property of 2-(2-hydroxy-5-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(2-hydroxy-5-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline

There total 2 articles about 2-(2-hydroxy-5-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1,10-phenanthroline-5,6-dione (27318-90-7) + 5-bromosalicyclaldehyde (1761-61-1) → 2-(2-hydroxy-5-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline (1420904-53-5)

Guidance literature:

With ammonium acetate; acetic acid; at 120 ℃; for 30h;

DOI:10.1039/d1dt01604k

Reference yield: 73.0%

1,10-o-phenanthroline-5,6-diamine (168646-54-6) + 5-bromosalicyclaldehyde (1761-61-1) → 2-(2-hydroxy-5-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline (1420904-53-5)

Guidance literature:

With dihydrogen peroxide; acetic acid; In ethanol; for 12h; Reflux;

DOI:10.1016/j.ica.2015.05.019

Reference yield: 93.0%

ammonium hexafluorophosphate + [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 2-(2-hydroxy-5-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline (1420904-53-5) → [(η6-p-cymene)RuCl(K2-N,N-4-bromo-2-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol)]PF6

Guidance literature:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; 2-(2-hydroxy-5-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline; In methanol; dichloromethane; at 20 ℃; for 2h; Sonication;

ammonium hexafluorophosphate; In methanol; dichloromethane; at 20 ℃; for 1.5h; Sonication;

DOI:10.1039/d1dt01604k

upstream raw materials:

1,10-phenanthroline-5,6-dione

5-bromosalicyclaldehyde

1,10-o-phenanthroline-5,6-diamine

Downstream raw materials:

C₃₈H₂₄Br₂ClCoN₈O₃⁽¹⁺⁾*Cl^(1-)

C₃₈H₂₂Br₂Cl₄N₈Ni₂O₂

C₃₈H₂₂Br₂Cl₂CuN₈O₂