ethyl 4-[7-(tert-butyldimethylsilanyloxymethyl)-1-methylindan-4-yl]benzoate

Base Information

Chemical Name:ethyl 4-[7-(tert-butyldimethylsilanyloxymethyl)-1-methylindan-4-yl]benzoate
CAS No.:1477494-13-5
Molecular Formula:C₂₆H₃₆O₃Si
Molecular Weight:424.656
Hs Code.:

Synonyms:ethyl 4-[7-(tert-butyldimethylsilanyloxymethyl)-1-methylindan-4-yl]benzoate

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Chemical Property of ethyl 4-[7-(tert-butyldimethylsilanyloxymethyl)-1-methylindan-4-yl]benzoate

Chemical Property:

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Technology Process of ethyl 4-[7-(tert-butyldimethylsilanyloxymethyl)-1-methylindan-4-yl]benzoate

There total 4 articles about ethyl 4-[7-(tert-butyldimethylsilanyloxymethyl)-1-methylindan-4-yl]benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 1477494-12-4
ethyl 4-[7-(tert-butyldimethylsilanyloxymethyl)-1-methyl-6-trifluoromethanesulfonyloxyindan-4-yl]benzoate

: 1477494-13-5
ethyl 4-[7-(tert-butyldimethylsilanyloxymethyl)-1-methylindan-4-yl]benzoate

Guidance literature:: With formic acid; palladium diacetate; triethylamine; triphenylphosphine; In N,N-dimethyl-formamide; at 60 ℃; for 2h;
DOI:10.1055/s-0033-1339484

Reference yield:

: 1477494-06-6
ethyl 7-(4-ethoxycarbonylphenyl)-5-hydroxy-3-methylindan-4-carboxylate

: 1477494-13-5
ethyl 4-[7-(tert-butyldimethylsilanyloxymethyl)-1-methylindan-4-yl]benzoate

Guidance literature:: Multi-step reaction with 4 steps

1: dimethylsulfide borane complex / tetrahydrofuran / 17 h / 0 - 20 °C

2: triethylamine / dichloromethane / 1.5 h / 0 - 20 °C

3: triethylamine / dichloromethane / 4 h / 0 - 20 °C

4: triphenylphosphine; triethylamine; formic acid; palladium diacetate / N,N-dimethyl-formamide / 2 h / 60 °C

With formic acid; dimethylsulfide borane complex; palladium diacetate; triethylamine; triphenylphosphine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1055/s-0033-1339484

Reference yield:

: 1477494-08-8
ethyl 4-(6-hydroxy-7-hydroxymethyl-1-methylindan-4-yl)benzoate

: 1477494-13-5
ethyl 4-[7-(tert-butyldimethylsilanyloxymethyl)-1-methylindan-4-yl]benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: triethylamine / dichloromethane / 1.5 h / 0 - 20 °C

2: triethylamine / dichloromethane / 4 h / 0 - 20 °C

3: triphenylphosphine; triethylamine; formic acid; palladium diacetate / N,N-dimethyl-formamide / 2 h / 60 °C

With formic acid; palladium diacetate; triethylamine; triphenylphosphine; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1055/s-0033-1339484