(E)-But-2-enoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

Base Information

Chemical Name:(E)-But-2-enoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester
CAS No.:137585-71-8
Molecular Formula:C₁₈H₂₂O₅
Molecular Weight:318.37
Hs Code.:

Synonyms:(E)-But-2-enoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-But-2-enoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

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Technology Process of (E)-But-2-enoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

There total 1 articles about (E)-But-2-enoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 18439-39-9
2,2-dimethyl-5-phenylmethyl-(3aR,5R,6aR)-perhydrofuro[2,3-d][1,3]-dioxol-(6S)-ol

: 625-35-4,3488-22-0,10487-71-5
trans-chrotonyl chloride

: 137585-71-8
(E)-But-2-enoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 0 ℃;
DOI:10.1016/S0957-4166(00)82200-4

Reference yield:

: 13125-66-1
n-heptylmagnesium bromide

: 137585-71-8
(E)-But-2-enoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

: 137585-81-0,137586-09-5
3-Methyl-decanoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

Guidance literature:: With copper(I) bromide dimethylsulfide complex; Yield given. Multistep reaction; 1.) THF, -78 deg C, 10 min, 2.) THF, -78 deg C, 2 h;
DOI:10.1016/S0957-4166(00)82200-4

Reference yield:

: 137585-71-8
(E)-But-2-enoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

: 1730-25-2
allylmagnesium bromide

: 137585-79-6,137586-08-4
3-Methyl-hex-5-enoic acid (3aR,5R,6S,6aR)-5-benzyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

Guidance literature:: With copper(I) bromide dimethylsulfide complex; Yield given. Multistep reaction; 1.) THF, -78 deg C, 10 min, 2.) THF, -78 deg C, 2 h;
DOI:10.1016/S0957-4166(00)82200-4