oxido-phenethyl-phenethylimino-azanium

Base Information

• Chemical Name: oxido-phenethyl-phenethylimino-azanium
• CAS No.: 77630-69-4
• Molecular Formula: C16H18 N2 O
• Molecular Weight: 254.332
• Hs Code.: 2927000090
• Mol file: 77630-69-4.mol

Synonyms:Diazene,bis(2-phenylethyl)-, 1-oxide (9CI)

Chemical Property of oxido-phenethyl-phenethylimino-azanium

Chemical Property:

• Vapor Pressure: 1.46E-06mmHg at 25°C
• Boiling Point: 410.2°C at 760 mmHg
• Flash Point: 201.9°C
• PSA: 41.11000
• Density: 1.03g/cm³
• LogP: 3.95750

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of oxido-phenethyl-phenethylimino-azanium

There total 2 articles about oxido-phenethyl-phenethylimino-azanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

phenethylamine (64-04-0) → Phenylacetaldehyde oxime (7028-48-0) + 1,1'-azoxybis(2-phenylethane) (77630-69-4) + 1-nitroso-2-phenylethane dimer (3378-37-8,26049-09-2)

Guidance literature:

With dihydrogen peroxide; methyltrioxorhenium(VII); In isopropyl alcohol; at 20 ℃; for 0.5h;

DOI:10.1246/bcsj.70.877

Reference yield: 26.0%

phenethylamine (64-04-0) → Phenylacetaldehyde oxime (7028-48-0) + (E)-diphenethyl-diazene-N,N'-dioxide (3378-37-8,26049-09-2) + phenylacetaldehyde (122-78-1) + 1,1'-azoxybis(2-phenylethane) (77630-69-4)

Guidance literature:

With dihydrogen peroxide; poly(N-isopropylacrylamide) based tungsten catalyst; In toluene; at 60 ℃; Product distribution;

DOI:10.1016/j.tetlet.2007.04.071

upstream raw materials:

phenethylamine

Refernces

• 1、 Yamazaki, Shigekazu. "Methyltrioxorhenium-Catalyzed Oxidation of Secondary and Primary Amines with Hydrogen Peroxide". . p. 877 - 883. Retrieved 2007/10/03.
• 2、 Zajac, Walter W.,Walters, Thomas R.,Woods, James M.. "Oxidation of Primary Aliphatic Amines to C-Nitroso Dimers". . p. 808 - 810. Retrieved 2007/10/02.