acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester

Base Information

Chemical Name:acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester
CAS No.:851592-79-5
Molecular Formula:C₃₁H₄₂O₆Si
Molecular Weight:538.756
Hs Code.:

acetic acid 1-{1-[2-(<i>tert</i>-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6<i>H</i>-[1,3]dioxin-4-yl)-ethyl ester

Synonyms:acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester

Suppliers and Price of acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester

There total 8 articles about acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethanol

: 108-24-7
acetic anhydride

: 851592-79-5
acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester

Guidance literature:: With pyridine; dmap; In dichloromethane; at -78 - -10 ℃; for 16.5h;
DOI:10.1021/ol050270s

Reference yield:

: 851592-83-1
phenylsulfanyl-acetic acid 1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyl ester

: 851592-79-5
acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester

Guidance literature:: Multi-step reaction with 7 steps

1.1: LDA / tetrahydrofuran; hexane / -78 °C

1.2: 94 percent / tetrahydrofuran; hexane / -78 - -35 °C

2.1: BF₃*OEt₂ / CH₂Cl₂ / 0.25 h / 0 °C

3.1: 91 percent / m-CPBA / CH₂Cl₂ / 0.42 h / -78 °C

4.1: 22 percent / P(OEt)3 / m-xylene / 1 h / Heating

5.1: 76 percent / NaHMDS / tetrahydrofuran / 0.02 h / -78 °C

6.1: DIBAL-H / CH₂Cl₂; hexane / 0.83 h / -78 °C

7.1: 285 mg / pyridine; DMAP / CH₂Cl₂ / 16.5 h / -78 - -10 °C

With pyridine; dmap; boron trifluoride diethyl etherate; sodium hexamethyldisilazane; diisobutylaluminium hydride; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; triethyl phosphite; In tetrahydrofuran; hexane; dichloromethane; m-xylene;
DOI:10.1021/ol050270s

Reference yield:

: 851592-85-3
(5-methyl-[1,3]dioxan-4-ylidene)-acetic acid 1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyl ester

: 851592-79-5
acetic acid 1-{1-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-but-3-enyloxy}-2-(5-methyl-6H-[1,3]dioxin-4-yl)-ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / NaHMDS / tetrahydrofuran / 0.02 h / -78 °C

2: DIBAL-H / CH₂Cl₂; hexane / 0.83 h / -78 °C

3: 285 mg / pyridine; DMAP / CH₂Cl₂ / 16.5 h / -78 - -10 °C

With pyridine; dmap; sodium hexamethyldisilazane; diisobutylaluminium hydride; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ol050270s