3-chloro-3,3-(1,3-diphenylphosphinopropane)-3,1,2-closo-dicarbollylruthenium

Base Information

Chemical Name:3-chloro-3,3-(1,3-diphenylphosphinopropane)-3,1,2-closo-dicarbollylruthenium
CAS No.:917598-26-6
Molecular Formula:C₂₉H₃₇B₉ClP₂Ru
Molecular Weight:681.382
Hs Code.:

Synonyms:3-chloro-3,3-(1,3-diphenylphosphinopropane)-3,1,2-closo-dicarbollylruthenium

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Chemical Property of 3-chloro-3,3-(1,3-diphenylphosphinopropane)-3,1,2-closo-dicarbollylruthenium

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Technology Process of 3-chloro-3,3-(1,3-diphenylphosphinopropane)-3,1,2-closo-dicarbollylruthenium

There total 5 articles about 3-chloro-3,3-(1,3-diphenylphosphinopropane)-3,1,2-closo-dicarbollylruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 3,3-bis(triphenylphosphine)-3-chloro-3-hydrido-3,1,2-closo-dicarbollylruthenium

: 7688-25-7
1,4-di(diphenylphosphino)-butane

: 917598-26-6
3-chloro-3,3-(1,3-diphenylphosphinopropane)-3,1,2-closo-dicarbollylruthenium

Guidance literature:: In benzene; (Ar); stirring soln. of ruthenium compd. and phosphine deriv. in benzeneat 80°C for 1.5 h; heating obtained 1:1 mixture of ruthenium com pds. at reflux for 6 h, monitoring by HPLC; evapn., chromy. (silica gel, benzene), recrystn. (CH2Cl2/hexane (3:1)), ESR;
DOI:10.1007/s11172-006-0394-9

Reference yield: 44.0%

: chlorobis(1,3-diphenylphosphinopropane)-exo-nido-[10-hydroorthocarborane-5,6,10-tris(hydrido)]ruthenium

: 917598-26-6
3-chloro-3,3-(1,3-diphenylphosphinopropane)-3,1,2-closo-dicarbollylruthenium

Guidance literature:: In benzene; under Ar atm.; soln. of Ru complex in benzene was stirred at 22°Cfor about 60 h; refluxed in benzene for 3 h; solvent removed (vac.); residue chromd. on silica gel column (C6H6 as eluent); elem. anal.;
DOI:10.1007/s11172-006-0151-0

Reference yield:

: chlorobis(triphenylphosphine)-exo-nido-[10-hydroorthocarborane-5,6,10-tris(hydro)]ruthenium(II)

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 917598-26-6
3-chloro-3,3-(1,3-diphenylphosphinopropane)-3,1,2-closo-dicarbollylruthenium

: 917598-25-5
3-chloro-3,3-(1,3-diphenylphosphinopropane)-3-hydro-3,1,2-closo-dicarbollylruthenium

Guidance literature:: In benzene; (Ar); stirring soln. of ruthenium compd. and phosphine deriv. in benzeneat room temp. for 144 h; evapn., chromy. (silica gel, benzene/hexane (1:1)), HPLC;
DOI:10.1007/s11172-006-0394-9