Tetrachloroplatinate(II)

Base Information

• Chemical Name: Tetrachloroplatinate(II)
• CAS No.: 13965-91-8
• Molecular Formula: Cl₄Pt
• Molecular Weight: 336.892
• Mol file: 13965-91-8.mol

Synonyms:ammonium tetrachloroplatinite(II);diammonium tetrachloroplatinate;dipotassium tetrachloroplatinate;potassium tetrachloroplatinate;tetrachloroplatinate;tetrachloroplatinate, diammonium salt;tetrachloroplatinate, dipotassium salt;tetrachloroplatinate, dirubidium salt;tetrachloroplatinate, potassium salt, (195)Pt-labeled;tetrachloroplatinate, sodium salt;tetrachloroplatinate, tetraammonium salt;tetrachloroplatinum dipotassium salt

Chemical Property of Tetrachloroplatinate(II)

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 336.837255
• Heavy Atom Count: 5
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Cl-].[Pt+2]

Technology Process of Tetrachloroplatinate(II)

There total 23 articles about Tetrachloroplatinate(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

dihydrogen hexachloroplatinate(IV) hexahydrate + isopropyl alcohol (67-63-0,8013-70-5) → tetrachloroplatinum(II) (13965-91-8) + {(C3H6)PtCl3}(1-)

Guidance literature:

In water; isopropyl alcohol; byproducts: propene; redn. of Pt-compd. with isopropanol at room temp. after 131 h; monitored by NMR; Kinetics;

Reference yield:

tetrammineplatinum(II) chloride → transplatin (26035-31-4,14913-33-8,15663-27-1) + tetrachloroplatinum(II) (13965-91-8) + {PtaCl3}(1-) + Pt(NH3)Cl3(1+) + Pt(NH3)2Cl2#Pt(NH3)2Cl2

Guidance literature:

With oxygen; In hydrogenchloride; thermostatting a soln. of the complex in 1 M HCl at 150°C for 1 h, yellow color after 30 - 40 min, cooling, pptn.; monitoring by electronic absorption spectroscopy, after 1 h: 81% combined yield of the diammine complexes, 18% Pt(NH3)Cl3(1-) and 0.5% Pt(IV), after 2 h: 64% combined yield of the diammine complexes and 35% Pt(NH3)Cl3(1-), after 4 h: > 99% PtCl4(2-);

Reference yield:

hexachloroplatinate(II) (16871-54-8) → tetrachloroplatinum(II) (13965-91-8)

Guidance literature:

With sodium chloride; ascorbic acid; In water; byproducts: dehydroascorbic acid; under Ar, protected from exposure to daylight; Pt complex in aq. acetateor phosphate buffer contg. Na2H2(edta) (pH 4.01-7.15) reduced with L-as corbic acid at 25°C; ionic strength 1.0 M (NaCl); monitored spectrophotometrically; Kinetics;

DOI:10.1016/S0020-1693(01)00762-9

upstream raw materials:

[Pt(CH₃)Cl₅]^(2-)

palladium

isopropyl alcohol

trichloro(ethene)platinate(II)^(1-)

Downstream raw materials:

PtCl₂((C₆H₅)2PC₆H₄NHC(O)C₆⁽²⁾H₅)2

Pt(P(C₂H₅)(C₆H₅)2)4⁽²⁺⁾*PtCl₄^(2-)=[Pt(P(C₂H₅)(C₆H₅)2)4][PtCl₄]

Pt(P(C₂H₅)2(C₆H₅))4⁽²⁺⁾*PtCl₄^(2-)=[Pt(P(C₂H₅)2(C₆H₅))4][PtCl₄]