(E)-2-Triisopropylsilanyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dien-1-one

Base Information

Chemical Name:(E)-2-Triisopropylsilanyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dien-1-one
CAS No.:216452-09-4
Molecular Formula:C₂₂H₃₈OSi
Molecular Weight:346.629
Hs Code.:

Synonyms:(E)-2-Triisopropylsilanyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dien-1-one

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Chemical Property of (E)-2-Triisopropylsilanyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dien-1-one

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Technology Process of (E)-2-Triisopropylsilanyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dien-1-one

There total 4 articles about (E)-2-Triisopropylsilanyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dien-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: (E)-1-Diazo-1-triisopropylsilanyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-but-3-en-2-one

: 216452-09-4
(E)-2-Triisopropylsilanyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dien-1-one

Guidance literature:: In benzene; at 30 - 35 ℃; for 2h; Irradiation;
DOI:10.1021/jo981289u

Reference yield:

: 79-77-6,14901-07-6
(E)-β-ionone

: 216452-09-4
(E)-2-Triisopropylsilanyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dien-1-one

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) lithium hexamethyldisilazide / 1.) THF, hexane, -78 deg C, 30 min, 2.) THF, hexane, -78 deg C, 10 min

2: 2.18 g / triethylamine, methanesulfonyl azide / acetonitrile; H₂O / 3 h / 25 °C

3: 87 percent / diisopropylethylamine / diethyl ether; hexane / 1.5 h / 0 - 25 °C

4: 61 percent / benzene / 2 h / 30 - 35 °C / Irradiation

With triethylamine; N-ethyl-N,N-diisopropylamine; Methanesulfonyl azide; lithium hexamethyldisilazane; In diethyl ether; hexane; water; acetonitrile; benzene;
DOI:10.1021/jo981289u

Reference yield:

: 29208-43-3
1-diazo-4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one

: 216452-09-4
(E)-2-Triisopropylsilanyl-4-(2,6,6-trimethyl-cyclohex-1-enyl)-buta-1,3-dien-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / diisopropylethylamine / diethyl ether; hexane / 1.5 h / 0 - 25 °C

2: 61 percent / benzene / 2 h / 30 - 35 °C / Irradiation

With N-ethyl-N,N-diisopropylamine; In diethyl ether; hexane; benzene;
DOI:10.1021/jo981289u