methyl 4-O-benzoyl-2,3-di-O-toluene-p-sulfonyl-6-deoxy-α-D-glucopyranoside

Base Information

Chemical Name:methyl 4-O-benzoyl-2,3-di-O-toluene-p-sulfonyl-6-deoxy-α-D-glucopyranoside
CAS No.:116809-48-4
Molecular Formula:C₂₈H₃₀O₁₀S₂
Molecular Weight:590.672
Hs Code.:

Synonyms:methyl 4-O-benzoyl-2,3-di-O-toluene-p-sulfonyl-6-deoxy-α-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 4-O-benzoyl-2,3-di-O-toluene-p-sulfonyl-6-deoxy-α-D-glucopyranoside

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Technology Process of methyl 4-O-benzoyl-2,3-di-O-toluene-p-sulfonyl-6-deoxy-α-D-glucopyranoside

There total 3 articles about methyl 4-O-benzoyl-2,3-di-O-toluene-p-sulfonyl-6-deoxy-α-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 65556-00-5
methyl 4,6-di-O-benzylidene-2,3-di-O-tosyl-α-D-glucopyranoside

: 116809-48-4
methyl 4-O-benzoyl-2,3-di-O-toluene-p-sulfonyl-6-deoxy-α-D-glucopyranoside

: methyl 6-O-benzoyl-2,3-di-O-toluene-p-sulfonyl-4-deoxy-α-D-glucopyranoside

Guidance literature:: With 2,2-bis(tert-butylperoxy)butane; tri-tert-butoxysilanethiol; In octane; chlorobenzene; for 2h; Heating;
DOI:10.1039/b212303g

Reference yield:

: 116809-47-3
Benzoic acid (2S,3R,4S,5R,6S)-2-iodomethyl-6-methoxy-4,5-bis-(toluene-4-sulfonyloxy)-tetrahydro-pyran-3-yl ester

: 116809-48-4
methyl 4-O-benzoyl-2,3-di-O-toluene-p-sulfonyl-6-deoxy-α-D-glucopyranoside

Guidance literature:: With hydrogen; sodium acetate; palladium on activated charcoal; In ethanol; water; ethyl acetate; for 16h; Yield given;
DOI:10.1021/jo00265a033

Reference yield:

: 101155-76-4
methyl 2,3-di-O-p-toluenesulfonyl-4-O-benzoyl-6-bromo-6-deoxy-α-D-glucopyranoside

: 116809-48-4
methyl 4-O-benzoyl-2,3-di-O-toluene-p-sulfonyl-6-deoxy-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 11.5 g / NaI / acetone / 16 h / Heating

2: NaOAc, hydrogen / palladium on carbon / ethyl acetate; ethanol; H₂O / 16 h

With hydrogen; sodium acetate; sodium iodide; palladium on activated charcoal; In ethanol; water; ethyl acetate; acetone;
DOI:10.1021/jo00265a033