1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde

Base Information

Chemical Name:1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde
CAS No.:912364-76-2
Molecular Formula:C₂₄H₂₈O₂Si
Molecular Weight:376.571
Hs Code.:

1-(<i>tert</i>-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde

Synonyms:1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde

Suppliers and Price of 1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde

There total 3 articles about 1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 912364-75-1
[1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienyl]-methanol

: 912364-76-2
1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde

Guidance literature:: With oxalyl dichloride; TEA; dimethyl sulfoxide; In dichloromethane; at -78 - 20 ℃;
DOI:10.1016/j.tetlet.2006.07.010

Reference yield:

: 74269-63-9
(1-Benzyloxymethyl-cyclohexa-2,5-dienyl)-methanol

: 912364-76-2
1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: Li / liquid ammonia / 0.67 h / -33 °C

2: imidazole / CH₂Cl₂ / 10 h / 0 °C

3: 94 percent / (COCl)2; DMSO; TEA / CH₂Cl₂ / -78 - 20 °C

With 1H-imidazole; oxalyl dichloride; TEA; lithium; dimethyl sulfoxide; In dichloromethane; ammonia; 1: Birch reduction / 3: Swern oxidation;
DOI:10.1016/j.tetlet.2006.07.010

Reference yield:

: cyclohexa-2,5-diene-1,1-diyldimethanol

: 912364-76-2
1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: imidazole / CH₂Cl₂ / 10 h / 0 °C

2: 94 percent / (COCl)2; DMSO; TEA / CH₂Cl₂ / -78 - 20 °C

With 1H-imidazole; oxalyl dichloride; TEA; dimethyl sulfoxide; In dichloromethane; 2: Swern oxidation;
DOI:10.1016/j.tetlet.2006.07.010