phenyl 4-(4-butoxyphenylsulfanyl)-2'-(tridec-2-ynoyl)biphenyl-3-sulfonate

Base Information

Chemical Name:phenyl 4-(4-butoxyphenylsulfanyl)-2'-(tridec-2-ynoyl)biphenyl-3-sulfonate
CAS No.:936833-32-8
Molecular Formula:C₄₁H₄₆O₅S₂
Molecular Weight:682.945
Hs Code.:

Synonyms:phenyl 4-(4-butoxyphenylsulfanyl)-2'-(tridec-2-ynoyl)biphenyl-3-sulfonate

Suppliers and Price of phenyl 4-(4-butoxyphenylsulfanyl)-2'-(tridec-2-ynoyl)biphenyl-3-sulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenyl 4-(4-butoxyphenylsulfanyl)-2'-(tridec-2-ynoyl)biphenyl-3-sulfonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenyl 4-(4-butoxyphenylsulfanyl)-2'-(tridec-2-ynoyl)biphenyl-3-sulfonate

There total 7 articles about phenyl 4-(4-butoxyphenylsulfanyl)-2'-(tridec-2-ynoyl)biphenyl-3-sulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 832725-69-6
phenyl 4-(4-butoxyphenylsulfanyl)-2'-(1-hydroxytridec-2-ynyl)biphenyl-3-sulfonate

: 936833-32-8
phenyl 4-(4-butoxyphenylsulfanyl)-2'-(tridec-2-ynoyl)biphenyl-3-sulfonate

Guidance literature:: With Dess-Martin periodane; In dichloromethane; at 0 ℃; for 2h;
DOI:10.1016/j.bmc.2007.02.048

Reference yield:

: 158153-88-9
phenyl 2,5-dibromobenzenesulfonate

: 936833-32-8
phenyl 4-(4-butoxyphenylsulfanyl)-2'-(tridec-2-ynoyl)biphenyl-3-sulfonate

Guidance literature:: Multi-step reaction with 5 steps

1.1: 77 percent / ethyldiisopropylamine / dimethylformamide / 6 h / 80 °C

2.1: 82 percent / DBU / dimethylformamide / 4 h / 60 °C

3.1: 90 percent / aq. K₂CO₃ / Pd(PPh₃)4 / 1,2-dimethoxy-ethane / 5 h / 60 °C

4.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / -45 °C

4.2: 83 percent / tetrahydrofuran; hexane / 1 h / -45 °C

5.1: 85 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 0 °C

With n-butyllithium; potassium carbonate; Dess-Martin periodane; 1,8-diazabicyclo[5.4.0]undec-7-ene; N-ethyl-N,N-diisopropylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,2-dimethoxyethane; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2007.02.048

Reference yield:

: 832725-65-2
phenyl 5-bromo-2-(4-hydroxyphenylsulfanyl)benzenesulfonate

: 936833-32-8
phenyl 4-(4-butoxyphenylsulfanyl)-2'-(tridec-2-ynoyl)biphenyl-3-sulfonate

Guidance literature:: Multi-step reaction with 4 steps

1.1: 82 percent / DBU / dimethylformamide / 4 h / 60 °C

2.1: 90 percent / aq. K₂CO₃ / Pd(PPh₃)4 / 1,2-dimethoxy-ethane / 5 h / 60 °C

3.1: n-BuLi / tetrahydrofuran; hexane / 0.17 h / -45 °C

3.2: 83 percent / tetrahydrofuran; hexane / 1 h / -45 °C

4.1: 85 percent / Dess-Martin periodinane / CH₂Cl₂ / 2 h / 0 °C

With n-butyllithium; potassium carbonate; Dess-Martin periodane; 1,8-diazabicyclo[5.4.0]undec-7-ene; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,2-dimethoxyethane; hexane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.bmc.2007.02.048