(2,2',6,6'-tetrakis(dideuteriomethyl)-3,3',4,4',5,5'-hexamethyldiphenyl)diazomethane

Base Information

Chemical Name:(2,2',6,6'-tetrakis(dideuteriomethyl)-3,3',4,4',5,5'-hexamethyldiphenyl)diazomethane
CAS No.:191727-65-8
Molecular Formula:C₂₃H₃₀N₂
Molecular Weight:342.441
Hs Code.:

Synonyms:(2,2',6,6'-tetrakis(dideuteriomethyl)-3,3',4,4',5,5'-hexamethyldiphenyl)diazomethane

Suppliers and Price of (2,2',6,6'-tetrakis(dideuteriomethyl)-3,3',4,4',5,5'-hexamethyldiphenyl)diazomethane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2,2',6,6'-tetrakis(dideuteriomethyl)-3,3',4,4',5,5'-hexamethyldiphenyl)diazomethane

Chemical Property:

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Technology Process of (2,2',6,6'-tetrakis(dideuteriomethyl)-3,3',4,4',5,5'-hexamethyldiphenyl)diazomethane

There total 10 articles about (2,2',6,6'-tetrakis(dideuteriomethyl)-3,3',4,4',5,5'-hexamethyldiphenyl)diazomethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 68818-74-6
1,3-dibromo-4,5,6-trimethylbenzene

: 191727-65-8
(2,2',6,6'-tetrakis(dideuteriomethyl)-3,3',4,4',5,5'-hexamethyldiphenyl)diazomethane

Guidance literature:: Multi-step reaction with 11 steps

1: 60 percent / dimethylformamide / Heating

2: 98 percent / H₂SO₄ / H₂O / 48 h / Heating

3: 40 percent / H₂SO₄ / Heating

4: 90 percent / LiAlD₄ / tetrahydrofuran / Heating

5: 73 percent / PBr₃ / dioxane / Ambient temperature

6: 91 percent / LiAlH₄ / tetrahydrofuran / Heating

7: 71 percent / Br₂, Fe/I₂ / CCl₄

8: 74 percent

9: 1.) n-BuLi / 1.) n-hexane, 2.) n-hexane

10: N₂O₄

11: LiAlH₄

With lithium aluminium tetrahydride; n-butyllithium; lithium aluminium deuteride; sulfuric acid; bromine; iodine; phosphorus tribromide; dinitrogen tetraoxide; iron; In tetrahydrofuran; 1,4-dioxane; tetrachloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/ja9635903

Reference yield:

: 51352-04-6
1,3-dicyano-4,5,6-trimethylbenzene

: 191727-65-8
(2,2',6,6'-tetrakis(dideuteriomethyl)-3,3',4,4',5,5'-hexamethyldiphenyl)diazomethane

Guidance literature:: Multi-step reaction with 10 steps

1: 98 percent / H₂SO₄ / H₂O / 48 h / Heating

2: 40 percent / H₂SO₄ / Heating

3: 90 percent / LiAlD₄ / tetrahydrofuran / Heating

4: 73 percent / PBr₃ / dioxane / Ambient temperature

5: 91 percent / LiAlH₄ / tetrahydrofuran / Heating

6: 71 percent / Br₂, Fe/I₂ / CCl₄

7: 74 percent

8: 1.) n-BuLi / 1.) n-hexane, 2.) n-hexane

9: N₂O₄

10: LiAlH₄

With lithium aluminium tetrahydride; n-butyllithium; lithium aluminium deuteride; sulfuric acid; bromine; iodine; phosphorus tribromide; dinitrogen tetraoxide; iron; In tetrahydrofuran; 1,4-dioxane; tetrachloromethane; water;
DOI:10.1021/ja9635903

Reference yield:

: 191727-57-8
1,3-bis(dideuteriomethyl)-4,5,6-trimethylbenzene

: 191727-65-8
(2,2',6,6'-tetrakis(dideuteriomethyl)-3,3',4,4',5,5'-hexamethyldiphenyl)diazomethane

Guidance literature:: Multi-step reaction with 5 steps

1: 71 percent / Br₂, Fe/I₂ / CCl₄

2: 74 percent

3: 1.) n-BuLi / 1.) n-hexane, 2.) n-hexane

4: N₂O₄

5: LiAlH₄

With lithium aluminium tetrahydride; n-butyllithium; bromine; iodine; dinitrogen tetraoxide; iron; In tetrachloromethane;
DOI:10.1021/ja9635903