(E)-[2-(2-(4-diphenylaminophenyl)vinyl)thien-5-yl](tert-butyl)silandiol

Base Information

Chemical Name:(E)-[2-(2-(4-diphenylaminophenyl)vinyl)thien-5-yl](tert-butyl)silandiol
CAS No.:1416081-19-0
Molecular Formula:C₂₈H₂₉NO₂SSi
Molecular Weight:471.695
Hs Code.:

Synonyms:(E)-[2-(2-(4-diphenylaminophenyl)vinyl)thien-5-yl](tert-butyl)silandiol

Suppliers and Price of (E)-[2-(2-(4-diphenylaminophenyl)vinyl)thien-5-yl](tert-butyl)silandiol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-[2-(2-(4-diphenylaminophenyl)vinyl)thien-5-yl](tert-butyl)silandiol

Chemical Property:

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Technology Process of (E)-[2-(2-(4-diphenylaminophenyl)vinyl)thien-5-yl](tert-butyl)silandiol

There total 3 articles about (E)-[2-(2-(4-diphenylaminophenyl)vinyl)thien-5-yl](tert-butyl)silandiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

: 98-13-5
Phenyltrichlorosilane

: 1042977-81-0
(E)-N,N-diphenyl-4-(2-(thiophen-2-yl)vinyl)aniline

: 1416081-19-0
(E)-[2-(2-(4-diphenylaminophenyl)vinyl)thien-5-yl](tert-butyl)silandiol

Guidance literature:: (E)-N,N-diphenyl-4-(2-(thiophen-2-yl)vinyl)aniline; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃; for 1.5h; Inert atmosphere;

Phenyltrichlorosilane; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 16h; Inert atmosphere;

With water; In tetrahydrofuran; hexane; Inert atmosphere;
DOI:10.1016/j.jorganchem.2012.10.012

Reference yield:

: 4181-05-9
4-(diphenylamino)benzaldehyde

: 1416081-19-0
(E)-[2-(2-(4-diphenylaminophenyl)vinyl)thien-5-yl](tert-butyl)silandiol

Guidance literature:: Multi-step reaction with 3 steps

1.1: potassium tert-butylate / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere

1.2: 16 h / -78 - 20 °C

2.1: iodine / chloroform / 16 h / 20 °C

3.1: n-butyllithium / tetrahydrofuran; hexane / 1.5 h / -78 - 0 °C / Inert atmosphere

3.2: 16 h / 0 - 20 °C / Inert atmosphere

3.3: Inert atmosphere

With n-butyllithium; potassium tert-butylate; iodine; In tetrahydrofuran; hexane; chloroform; 1.1: |Wittig Olefination / 1.2: |Wittig Olefination;
DOI:10.1016/j.jorganchem.2012.10.012

Reference yield:

: 302965-24-8
C₂₄H₁₉NS

: 1416081-19-0
(E)-[2-(2-(4-diphenylaminophenyl)vinyl)thien-5-yl](tert-butyl)silandiol

Guidance literature:: Multi-step reaction with 2 steps

1.1: iodine / chloroform / 16 h / 20 °C

2.1: n-butyllithium / tetrahydrofuran; hexane / 1.5 h / -78 - 0 °C / Inert atmosphere

2.2: 16 h / 0 - 20 °C / Inert atmosphere

2.3: Inert atmosphere

With n-butyllithium; iodine; In tetrahydrofuran; hexane; chloroform;
DOI:10.1016/j.jorganchem.2012.10.012