5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinatoiron(III)

Base Information

• Chemical Name: 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinatoiron(III)
• CAS No.: 60489-11-4
• Molecular Formula: C₄₄H₂₄FeN₄O₁₂S₄
• Molecular Weight: 984.805
• Mol file: 60489-11-4.mol

Synonyms:5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinatoiron(III)

Chemical Property of 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinatoiron(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinatoiron(III)

There total 3 articles about 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinatoiron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

meso-tetra(4-sulfonatophenyl)porphine tetrasodium dodecahydrate + iron(II) chloride → 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinatoiron(III) (60489-11-4)

Guidance literature:

With sodium hydroxide; In water; Reflux; Inert atmosphere;

DOI:10.1021/jacs.9b09161

Reference yield:

5,10,15,20-tetrakis(4-sulfonatophenyl)-21H,23H-porphine(4-) + iron(III) perchlorate → 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinatoiron(III) (60489-11-4)

Guidance literature:

In water; iron tetrasulfophenylporphyrin prepd. by dissolving of tetraphenylporphinetetrasulfonic acid and Fe(ClO4)3 in water; soln. refluxed at 100°C for 10 h; excess Fe(3+) eliminated by ion-exchange resin; elem. anal.;

DOI:10.1021/jp036054n

Reference yield:

5,10,15,20-tetrakis(4-sulfonatophenyl)-21H,23H-porphine(4-) + iron(II) chloride tetrahydrate → 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrinatoiron(III) (60489-11-4)

Guidance literature:

In N,N-dimethyl-formamide; chromy. on sephodex using of H2O as eluent;

DOI:10.1039/c1nj20400a

Downstream raw materials:

meso-tetra(4-sulfonatophenyl)porphyrinato)(nitrosyl)iron(III)

{Fe(II)(NO)(meso-tetrakis(p-sulfonatophenyl)porphyrinato)}^(3-)

Fe(C₅H₂NC₆H₄SO₃)4^(4-)

di-tert-butyl nitroxide