methyl O⁴,O⁶-(R)-benzylidene-2,3-methylsulfanylthiocarbonylazanediyl-α-D-2,3-dideoxy-allopyranoside

Base Information

• Chemical Name: methyl O⁴,O⁶-(R)-benzylidene-2,3-methylsulfanylthiocarbonylazanediyl-α-D-2,3-dideoxy-allopyranoside
• CAS No.: 7147-13-9
• Molecular Formula: C₁₆H₁₉NO₄S₂
• Molecular Weight: 353.463
• Mol file: 7147-13-9.mol

Synonyms:methyl O⁴,O⁶-(R)-benzylidene-2,3-methylsulfanylthiocarbonylazanediyl-α-D-2,3-dideoxy-allopyranoside

Chemical Property of methyl O⁴,O⁶-(R)-benzylidene-2,3-methylsulfanylthiocarbonylazanediyl-α-D-2,3-dideoxy-allopyranoside

Chemical Property:

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl O⁴,O⁶-(R)-benzylidene-2,3-methylsulfanylthiocarbonylazanediyl-α-D-2,3-dideoxy-allopyranoside

There total 1 articles about methyl O⁴,O⁶-(R)-benzylidene-2,3-methylsulfanylthiocarbonylazanediyl-α-D-2,3-dideoxy-allopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl O4,O6-(R)-benzylidene-O2-methanesulfonyl-3-methylsulfanylthiocarbonylamino-α-D-3-deoxy-altropyranoside (6945-62-6) → methyl O4,O6-(R)-benzylidene-2,3-methylsulfanylthiocarbonylazanediyl-α-D-2,3-dideoxy-allopyranoside (7147-13-9)

Guidance literature:

With sodium methylate; In methanol; 2-methoxy-ethanol;

DOI:10.1021/ja01502a070

Reference yield:

methyl O4,O6-(R)-benzylidene-2,3-methylsulfanylthiocarbonylazanediyl-α-D-2,3-dideoxy-allopyranoside (7147-13-9) → methyl 2,3-azanediyl-O4,O6-(R)-benzylidene-α-D-2,3-dideoxy-allopyranoside (3317-08-6)

Guidance literature:

Multistep reaction; (i) NaBH₄, AlCl₃, diglyme, (ii) (heating);

DOI:10.1021/ja01502a070

Reference yield:

methyl O4,O6-(R)-benzylidene-2,3-methylsulfanylthiocarbonylazanediyl-α-D-2,3-dideoxy-allopyranoside (7147-13-9) → methyl 2,3-benzoylazanediyl-O4,O6-(R)-benzylidene-α-D-2,3-dideoxy-allopyranoside (3778-08-3)

Guidance literature:

Multi-step reaction with 2 steps

1: (i) NaBH₄, AlCl₃, diglyme, (ii) (heating)

DOI:10.1021/ja01502a070

upstream raw materials:

methyl O⁴,O⁶-(R)-benzylidene-O²-methanesulfonyl-3-methylsulfanylthiocarbonylamino-α-D-3-deoxy-altropyranoside

Downstream raw materials:

methyl 2,3-azanediyl-O⁴,O⁶-(R)-benzylidene-α-D-2,3-dideoxy-allopyranoside

methyl 2,3-benzoylazanediyl-O⁴,O⁶-(R)-benzylidene-α-D-2,3-dideoxy-allopyranoside