2-(3,5-di-tert-butylphenyl)-7-(4-diphenylaminostyryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene

Base Information

Chemical Name:2-(3,5-di-tert-butylphenyl)-7-(4-diphenylaminostyryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene
CAS No.:1365479-81-7
Molecular Formula:C₆₇H₆₇N
Molecular Weight:886.276
Hs Code.:

Synonyms:2-(3,5-di-tert-butylphenyl)-7-(4-diphenylaminostyryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene

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Chemical Property of 2-(3,5-di-tert-butylphenyl)-7-(4-diphenylaminostyryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene

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Technology Process of 2-(3,5-di-tert-butylphenyl)-7-(4-diphenylaminostyryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene

There total 5 articles about 2-(3,5-di-tert-butylphenyl)-7-(4-diphenylaminostyryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 22385-77-9
1-bromo-3,5-di-tert-butylbenzene

: 1365480-11-0
2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolanyl)-7-(4-diphenylamino-styryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene

: 1365479-81-7
2-(3,5-di-tert-butylphenyl)-7-(4-diphenylaminostyryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate; In water; toluene; at 120 ℃; for 4h; Inert atmosphere;
DOI:10.1039/c2jm14869b

Reference yield:

: 439791-57-8
2,7-dibromo-(2',7'-di-tert-butyl)-9,9'-spirobifluorene

: 1365479-81-7
2-(3,5-di-tert-butylphenyl)-7-(4-diphenylaminostyryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene

Guidance literature:: Multi-step reaction with 4 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: 1 h / -78 °C

2.1: potassium tert-butylate / tetrahydrofuran / 1.17 h / 0 - 20 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

3.2: 3 h / -78 - 20 °C

4.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate / water; toluene / 4 h / 120 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; potassium tert-butylate; Aliquat 336; potassium carbonate; In tetrahydrofuran; hexane; water; toluene; 2.1: Horner-Wadsworth-Emmons reaction / 4.1: Suzuki reaction;
DOI:10.1039/c2jm14869b

Reference yield:

: 1365480-10-9
2-bromo-7-(4-diphenylaminostyryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene

: 1365479-81-7
2-(3,5-di-tert-butylphenyl)-7-(4-diphenylaminostyryl)-2',7'-di-tert-butyl-9,9'-spirobifluorene

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: 3 h / -78 - 20 °C

2.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; Aliquat 336; potassium carbonate / water; toluene / 4 h / 120 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; Aliquat 336; potassium carbonate; In tetrahydrofuran; hexane; water; toluene; 2.1: Suzuki reaction;
DOI:10.1039/c2jm14869b