Dolichantoside

Base Information

• Chemical Name: Dolichantoside
• CAS No.: 68727-52-6
• Molecular Formula: C28H36N2O9
• Molecular Weight: 544.602
• Mol file: 68727-52-6.mol

Synonyms:(4S,5R,6S)-4-((S)-2-Methyl-2,3,4,9-tetrahydro-1H-β-carbolin-1-ylmethyl)-6-((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy)-5-vinyl-5,6-dihydro-4H-pyran-3-carboxylic acid methyl ester;

Chemical Property of Dolichantoside

Chemical Property:

• PSA: 153.94000
• LogP: 0.67300

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Dolichantoside

There total 2 articles about Dolichantoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.2%

diazomethane (186581-53-3,908094-01-9,334-88-3) + 5-carboxystrictosidine → strictosidine (19456-89-4,20824-29-7) + dolichantoside (68727-52-6)

Guidance literature:

DOI:10.1248/cpb.45.1231

Reference yield:

[2-(1H-indol-3-yl)-ethyl]-methylamine (61-49-4) + secologanin (19351-63-4) → isodolichantoside + dolichantoside (68727-52-6)

Guidance literature:

DOI:10.1016/S0040-4039(98)01686-4

Reference yield:

dolichantoside (68727-52-6) → palicoside (123828-68-2)

Guidance literature:

With lithium hydroxide; In tetrahydrofuran;

DOI:10.1016/S0040-4039(98)01686-4

upstream raw materials:

diazomethane

[2-(1H-indol-3-yl)-ethyl]-methylamine

secologanin

Downstream raw materials:

palicoside

Refernces

• 1、 Takayama,Ohmori,Subhadhirasakul,Kitajima,Aimi. "Deeper insights into the stereostructure of strictosamide tetraacetate and methylisoalangiside tetraacetate, the key reference molecules in monoterpenoid indole- and isoquinoline glucoalkaloids". . p. 1231 - 1233. Retrieved 2007/10/03.