N-benzyl-N-{5-[4-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl]-pentyl}-benzenesulfonamide

Base Information

Chemical Name:N-benzyl-N-{5-[4-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl]-pentyl}-benzenesulfonamide
CAS No.:224324-99-6
Molecular Formula:C₄₃H₅₃NO₆SSi
Molecular Weight:740.048
Hs Code.:

<i>N</i>-benzyl-<i>N</i>-{5-[4-(<i>tert</i>-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3a,7a-dihydro-4<i>H</i>-[1,3]dioxolo[4,5-<i>c</i>]pyran-6-yl]-pentyl}-benzenesulfonamide

Synonyms:N-benzyl-N-{5-[4-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl]-pentyl}-benzenesulfonamide

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Chemical Property of N-benzyl-N-{5-[4-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl]-pentyl}-benzenesulfonamide

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Technology Process of N-benzyl-N-{5-[4-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl]-pentyl}-benzenesulfonamide

There total 8 articles about N-benzyl-N-{5-[4-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl]-pentyl}-benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: N-benzyl-N-{6-[2-(tert-butyl-diphenyl-silanyloxy)-1-(2,2-dimethyl-5-phenylsulfanyl-[1,3]dioxolan-4-yl)-ethoxy]-hept-6-enyl}-benzenesulfonamide

: 224324-99-6
N-benzyl-N-{5-[4-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl]-pentyl}-benzenesulfonamide

Guidance literature:: With 2,6-di-tert-butyl-4-methylpyridine; methyl trifluoromethanesulfonate; In dichloromethane;
DOI:10.1021/ja9843270

Reference yield:

: 4099-88-1,67814-68-0,70266-87-4,76249-50-8,76249-51-9,93451-15-1
(3aR,4S,6R,6aS)-6-(hydroxymethyl)-2,2-dimethylperhydrocyclopenta[d][1,3]dioxol-4-ol

: 224324-99-6
N-benzyl-N-{5-[4-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl]-pentyl}-benzenesulfonamide

Guidance literature:: Multi-step reaction with 6 steps

1: 92 percent

2: 95 percent / I₂

3: 1.) BF₃*Et₂O, 2.) MeONa / 1.) CH₂Cl₂, -78 deg C

4: DCC, DMAP / benzene

6: 76 percent / MeOTf, 2,6-di-t-butyl-4-methylpyridine / CH₂Cl₂

With dmap; 2,6-di-tert-butyl-4-methylpyridine; boron trifluoride diethyl etherate; iodine; sodium methylate; dicyclohexyl-carbodiimide; methyl trifluoromethanesulfonate; In dichloromethane; benzene;
DOI:10.1021/ja9843270

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 224324-99-6
N-benzyl-N-{5-[4-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3a,7a-dihydro-4H-[1,3]dioxolo[4,5-c]pyran-6-yl]-pentyl}-benzenesulfonamide

Guidance literature:: Multi-step reaction with 6 steps

1: 92 percent

2: 95 percent / I₂

3: 1.) BF₃*Et₂O, 2.) MeONa / 1.) CH₂Cl₂, -78 deg C

4: DCC, DMAP / benzene

6: 76 percent / MeOTf, 2,6-di-t-butyl-4-methylpyridine / CH₂Cl₂

With dmap; 2,6-di-tert-butyl-4-methylpyridine; boron trifluoride diethyl etherate; iodine; sodium methylate; dicyclohexyl-carbodiimide; methyl trifluoromethanesulfonate; In dichloromethane; benzene;
DOI:10.1021/ja9843270