Technology Process of 6-<(tert-butyldiphenylsilyl)oxy>-1--2,4-tetradecadien-8-yne
There total 6 articles about 6-<(tert-butyldiphenylsilyl)oxy>-1--2,4-tetradecadien-8-yne which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
Multi-step reaction with 6 steps
1: oxalyl chloride, DMF / benzene / Ambient temperature
2: benzene; diethyl ether / -10 - -5 °C
3: Rh(OAc)2 / 1 h / Ambient temperature
4: CeCl3*5H2O, NaBH4 / propan-2-ol; H2O
5: pyridine / 0 °C
6: imidazole / dimethylformamide / Ambient temperature
With
rhodium(II) acetate; pyridine; 1H-imidazole; sodium tetrahydroborate; cerium(III) chloride; oxalyl dichloride; N,N-dimethyl-formamide;
In
diethyl ether; water; N,N-dimethyl-formamide; isopropyl alcohol; benzene;
DOI:10.1021/jo00356a004
- Guidance literature:
-
Multi-step reaction with 5 steps
1: benzene; diethyl ether / -10 - -5 °C
2: Rh(OAc)2 / 1 h / Ambient temperature
3: CeCl3*5H2O, NaBH4 / propan-2-ol; H2O
4: pyridine / 0 °C
5: imidazole / dimethylformamide / Ambient temperature
With
rhodium(II) acetate; pyridine; 1H-imidazole; sodium tetrahydroborate; cerium(III) chloride;
In
diethyl ether; water; N,N-dimethyl-formamide; isopropyl alcohol; benzene;
DOI:10.1021/jo00356a004
- Guidance literature:
-
Multi-step reaction with 4 steps
1: Rh(OAc)2 / 1 h / Ambient temperature
2: CeCl3*5H2O, NaBH4 / propan-2-ol; H2O
3: pyridine / 0 °C
4: imidazole / dimethylformamide / Ambient temperature
With
rhodium(II) acetate; pyridine; 1H-imidazole; sodium tetrahydroborate; cerium(III) chloride;
In
water; N,N-dimethyl-formamide; isopropyl alcohol;
DOI:10.1021/jo00356a004
