2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3R,4S)-disulfite

Base Information

• Chemical Name: 2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3R,4S)-disulfite
• CAS No.: 259137-53-6
• Molecular Formula: C₂₁H₂₆O₅SSi
• Molecular Weight: 418.586

Synonyms:2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3R,4S)-disulfite

Chemical Property of 2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3R,4S)-disulfite

Chemical Property:

Purity/Quality:

98% ^*data from raw suppliers

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Technology Process of 2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3R,4S)-disulfite

There total 3 articles about 2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3R,4S)-disulfite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3S,4S)-diol (215031-98-4) → 2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3R,4S)-disulfite (259137-53-6)

Guidance literature:

With pyridine; thionyl chloride; at 20 ℃;

DOI:10.1080/07328319908044614

Reference yield:

tert-butylchlorodiphenylsilane (58479-61-1) → 2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3R,4S)-disulfite (259137-53-6)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine / 0 °C

2: 1.04 g / SOCl₂; pyridine / 20 °C

With pyridine; thionyl chloride; 1: Substitution / 2: Cyclization;

DOI:10.1080/07328319908044614

Reference yield:

1,4-anhydro-D-ribitol (491-19-0,3169-91-3,3169-92-4,3999-31-3,39798-06-6,39999-42-3,41935-96-0,41936-38-3,51607-76-2,51607-78-4,53448-53-6,58716-62-4,106248-68-4,106707-70-4,120442-63-9) → 2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3R,4S)-disulfite (259137-53-6)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine / 0 °C

2: 1.04 g / SOCl₂; pyridine / 20 °C

With pyridine; thionyl chloride; 1: Substitution / 2: Cyclization;

DOI:10.1080/07328319908044614

upstream raw materials:

2(R)-(tert-butyldimethylsilyloxymethyl)tetrahydrofuran-(3S,4S)-diol

tert-butylchlorodiphenylsilane

1,4-anhydro-D-ribitol

Downstream raw materials:

2(R)-(tert-butyldimethylsilyloxymethyl)-4(R)-azidotetrahydrofuran-3(S)-ol

tert-butyl-(2,2-dioxo-tetrahydro-2λ⁶-furo[3,4-d][1,3,2]dioxathiol-4-ylmethoxy)-diphenyl-silane

1,4-anhydro-2-deoxy-2-<3,4-dihydro-2,4-dioxo-5-methyl-1(2H)-pyrimidinyl>-D-arabinitol

4(R)-(6-chloro-9H-purin-9-yl)-2(R)-(hydroxymethyl)tetrahydrofuran-3(S)-ol

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