cis,trans-Mo(CO)2(PPh3)2(η1-SO2)(NCCH3)

Base Information

• Chemical Name: cis,trans-Mo(CO)2(PPh3)2(η1-SO2)(NCCH3)
• CAS No.: 84500-97-0
• Molecular Formula: C₄₀H₃₃MoNO₄P₂S
• Molecular Weight: 781.66

Synonyms:cis,trans-Mo(CO)2(PPh3)2(η1-SO2)(NCCH3)

Chemical Property of cis,trans-Mo(CO)2(PPh3)2(η1-SO2)(NCCH3)

Chemical Property:

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Technology Process of cis,trans-Mo(CO)2(PPh3)2(η1-SO2)(NCCH3)

There total 2 articles about cis,trans-Mo(CO)2(PPh3)2(η1-SO2)(NCCH3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

cis,trans-Mo(CO)2(PPh3)2(NCMe)2 (23526-71-8) → cis,trans-Mo(CO)2(PPh3)2(η1-SO2)(NCCH3) (84500-97-0)

Guidance literature:

With SO₂; In acetonitrile; a rapid stream of SO2 was passed over a stirred slurry of the Mo-complex; stirred for 15 min while maintaining in a SO2 atmosphere; cooled overnight in a freezer; washed with CH3CN; dried briefly in vacuo;

DOI:10.1021/ja00345a035

Reference yield:

cis-[Mo(CO)2(NCMe)2(PPh3)2] (23526-71-8,64162-40-9) → cis,trans-Mo(CO)2(PPh3)2(MeCN)(η2-SO2) (84500-97-0,84501-08-6)

Guidance literature:

With sulfur dioxide;

DOI:10.1039/c39810000305

Reference yield: 86.0%

cis,trans-Mo(CO)2(PPh3)2(η1-SO2)(NCCH3) (84500-97-0) + cyclohexylamine (108-91-8,157973-60-9) → [Mo(CO)2(C6H11NH2)3(SO2)] + [Mo(CO)2(CyNH2)(PPh3)(μSO2)]2 (84500-99-2)

Guidance literature:

In dichloromethane; Mo-complex was treated with cyclohexylamine; 15 min; solution was reduced; was allowed to stand for 10 min; diethyl ether was added slowly; 10 min; washed with 1:1 ether-CH2Cl2; dried briefly in vacuo; X-ray diffraction;

DOI:10.1021/ja00345a035

upstream raw materials:

cis-[Mo(CO)2(NCMe)2(PPh₃)2]

cis,trans-Mo(CO)2(PPh₃)2(NCMe)2

Downstream raw materials:

Mo(CO)2(P(CH₃)2(C₆H₅))3(SO₂)

Mo(CO)2(P(CH₃)2(C₆H₅))3(SO₂)

Mo(CO)2(P(CH₃)2(C₆H₅))3(SO₂)

Mo(CO)2(P(CH₃)(C₆H₅)2)3(SO₂)

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