(2,6-C₆H₃(i)Pr₂NVCp(PMe₃)2

Base Information

Chemical Name:(2,6-C₆H₃(i)Pr₂NVCp(PMe₃)2
CAS No.:156975-33-6
Molecular Formula:C₂₃H₄₀NP₂V
Molecular Weight:443.466
Hs Code.:

(2,6-C<sub>6</sub>H<sub>3</sub>(i)Pr<sub>2</sub>NVCp(PMe<sub>3</sub>)2

Synonyms:(2,6-C₆H₃(i)Pr₂NVCp(PMe₃)2

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Chemical Property of (2,6-C₆H₃(i)Pr₂NVCp(PMe₃)2

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Technology Process of (2,6-C₆H₃(i)Pr₂NVCp(PMe₃)2

There total 1 articles about (2,6-C₆H₃(i)Pr₂NVCp(PMe₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 156975-32-5
(cyclopentadienyl)VCl₂[N-2,6-C₆H₃-((i)Pr)2]

: 594-09-2
trimethylphosphane

: 156975-33-6
(2,6-C₆H₃(i)Pr₂NVCp(PMe₃)2

Guidance literature:: With Mg; In tetrahydrofuran; mixt. of 1 equiv V-complex, 2 equiv PMe3, and a large excess of Mg in THF stirred (under Ar, room temp., 16 h); evapn. (vac.), extn. (pentane), green extract concd., cooled (-25°C, crystn. in two crops); elem. anal.;
DOI:10.1021/om00020a003

Reference yield: 61.0%

: 156975-33-6
(2,6-C₆H₃(i)Pr₂NVCp(PMe₃)2

: 16721-45-2
triphenyl(phenylmethylene)phosphorane

: (C₅H₅)V[P(CH₃)3](CHC₆H₅)[((CH₃)2CH)2C₆H₃N]

Guidance literature:: In toluene; byproducts: PMe3, PPh3; equimolar mixt. of the V-complex and PhCHPPh3 in toluene stirred (70°C, 16 h) with an occassional vacuum applied to remove PMe3; cooled (room temp.), addn. of solid CuCl (removal of free PPh3), mixt. stirred (room temp., 20 h), evapn. (vac.), brown residue extd. (pentane), combined extracts concd., cooled (-25°C, crystn. in two crops);elem. anal.;
DOI:10.1021/om00020a003

Reference yield:

: 683-73-8,25549-98-8
Ethylene-d4

: 156975-33-6
(2,6-C₆H₃(i)Pr₂NVCp(PMe₃)2

: (C₅H₅)V[P(CH₃)3][C₂⁽²⁾H₄][((CH₃)2CH)2C₆H₃N]

Guidance literature:: In not given; byproducts: PMe3; react. of the V-complex with C2D4 (1 atm) at a temp. between 25 and 50°C; elem. anal.;
DOI:10.1021/om00020a003