2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-9-(4-dodecyloxy-phenyl)-[1,10]phenanthroline

Base Information

• Chemical Name: 2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-9-(4-dodecyloxy-phenyl)-[1,10]phenanthroline
• CAS No.: 318981-55-4
• Molecular Formula: C₄₂H₅₄N₂O₂Si
• Molecular Weight: 646.988
• Mol file: 318981-55-4.mol

Synonyms:2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-9-(4-dodecyloxy-phenyl)-[1,10]phenanthroline

Chemical Property of 2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-9-(4-dodecyloxy-phenyl)-[1,10]phenanthroline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-9-(4-dodecyloxy-phenyl)-[1,10]phenanthroline

There total 4 articles about 2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-9-(4-dodecyloxy-phenyl)-[1,10]phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 33.0%

t-butyldimethylsilyl-4-bromophenol (67963-68-2) + 2-(4-dodecyloxy-phenyl)-[1,10]phenanthroline (318981-54-3) → 2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-9-(4-dodecyloxy-phenyl)-[1,10]phenanthroline (318981-55-4)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃;

DOI:10.1039/b307065b

Reference yield:

{p-[(tert-butyldimethylsilyl)oxy]phenyl}lithium + 2-(4-dodecyloxy-phenyl)-[1,10]phenanthroline (318981-54-3) → 2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-9-(4-dodecyloxy-phenyl)-[1,10]phenanthroline (318981-55-4)

Guidance literature:

{p-[(tert-butyldimethylsilyl)oxy]phenyl}lithium; 2-(4-dodecyloxy-phenyl)-[1,10]phenanthroline; In tetrahydrofuran; at 0 ℃; for 4h;

With water; In tetrahydrofuran;

With manganese(IV) oxide; In tetrahydrofuran; at 20 ℃; for 1h; Further stages.;

DOI:10.1039/b006174n

Reference yield:

1,10-Phenanthroline (66-71-7) → 2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-9-(4-dodecyloxy-phenyl)-[1,10]phenanthroline (318981-55-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 85 percent / t-BuLi / tetrahydrofuran; hexane / -78 - 0 °C

2: 33 percent / n-BuLi / tetrahydrofuran; hexane / -78 - 0 °C

With n-butyllithium; tert.-butyl lithium; In tetrahydrofuran; hexane;

DOI:10.1039/b307065b

upstream raw materials:

2-(4-dodecyloxy-phenyl)-[1,10]phenanthroline

t-butyldimethylsilyl-4-bromophenol

1,10-Phenanthroline

1-bromo-4-dodecyloxybenzene

Downstream raw materials:

4-[9-(4-dodecyloxy-phenyl)-[1,10]phenanthrolin-2-yl]-phenol