[Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(mtbpy-.vphi.-Ph)](hexafluorophosphate)

Base Information

• Chemical Name: [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(mtbpy-.vphi.-Ph)](hexafluorophosphate)
• CAS No.: 1008133-53-6
• Molecular Formula: C₄₇H₃₆IrN₄*F₆P
• Molecular Weight: 994.014

Synonyms:[Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(mtbpy-.vphi.-Ph)](hexafluorophosphate)

Chemical Property of [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(mtbpy-.vphi.-Ph)](hexafluorophosphate)

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Technology Process of [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(mtbpy-.vphi.-Ph)](hexafluorophosphate)

There total 1 articles about [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(mtbpy-.vphi.-Ph)](hexafluorophosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

[Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C2,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate) (1008133-51-4) + phenylboronic acid (98-80-6) → [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C2,N)(mtbpy-.vphi.-Ph)](hexafluorophosphate) (1008133-53-6)

Guidance literature:

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In water; dimethyl sulfoxide; byproducts: Pd; degassing mixt. of iridium compd., phenylboronic acid in DMSO and aq. soln. of Na2CO3 under N2, addn. of palladium compd., stirring for 18 h under N2 at 80°; cooling to room temp., addn. of CH3CN, filtration, addn. of filtrate to satd. aq. soln. of KPF6, centrifugation, washing with water, drying in vac., chromy. (silica, CH2Cl2/methanol from 100/0 to 99/1), elem. anal.;

DOI:10.1021/ic701788d

Reference yield: 99.0%

N-Bromosuccinimide (128-08-5) + [Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C2,N)(mtbpy-.vphi.-Ph)](hexafluorophosphate) (1008133-53-6) → [Ir(1-bromo-3,5-di(2-pyridyl)-2,6-dimethylbenzene-N,C4,N))(mtbpy-.vphi.-Ph)](hexafluorophosphate) (1008133-55-8)

Guidance literature:

In acetonitrile; stirirng mixt. of iridium compd. and N-bromosuccinimide in CH3CN under N2 for 20 h; addn. of CH3CN to dissolve ppt., addn. to satd. aq. soln. of KPF6, centrifugation, washing with water, drying in vac., elem. anal.;

DOI:10.1021/ic701788d

upstream raw materials:

[Ir(1,3-di(2-pyridyl)-4,6-dimethylbenzene-N,C₂,N)(4-(p-bromophenyl)-6-(m-tolyl)-2,2'-bipyridine(-H))](hexafluorophosphate)

phenylboronic acid

Downstream raw materials:

[Ir(1-bromo-3,5-di(2-pyridyl)-2,6-dimethylbenzene-N,C₄,N))(mtbpy-.vphi.-Ph)](hexafluorophosphate)

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