1-Bromomethyl-2,3,4,5-tetramethyl-6-(2,2,2-trichloro-ethyl)-benzene

Base Information

• Chemical Name: 1-Bromomethyl-2,3,4,5-tetramethyl-6-(2,2,2-trichloro-ethyl)-benzene
• CAS No.: 70130-76-6
• Molecular Formula: C₁₃H₁₆BrCl₃
• Molecular Weight: 358.533
• Mol file: 70130-76-6.mol

Synonyms:1-Bromomethyl-2,3,4,5-tetramethyl-6-(2,2,2-trichloro-ethyl)-benzene

Chemical Property of 1-Bromomethyl-2,3,4,5-tetramethyl-6-(2,2,2-trichloro-ethyl)-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-Bromomethyl-2,3,4,5-tetramethyl-6-(2,2,2-trichloro-ethyl)-benzene

There total 1 articles about 1-Bromomethyl-2,3,4,5-tetramethyl-6-(2,2,2-trichloro-ethyl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Bromotrichloromethane (75-62-7) + 1,2,5,6-Tetramethyl-3,4-dimethylenetricyclo<3.1.0.0(2,6)>hexan (50590-86-8) → 1-Bromomethyl-2,3,4,5-tetramethyl-6-(2,2,2-trichloro-ethyl)-benzene (70130-76-6) + (1S,5R,6R)-6-Bromo-1,2,5,6-tetramethyl-4-methylene-3-(2,2,2-trichloro-ethyl)-bicyclo[3.1.0]hex-2-ene (70130-75-5)

Guidance literature:

Me₃NFe(CO)9; for 3h; Yield given. Yields of byproduct given; Ambient temperature;

DOI:10.1021/jo01308a003

Reference yield: 78.0%

1-Bromomethyl-2,3,4,5-tetramethyl-6-(2,2,2-trichloro-ethyl)-benzene (70130-76-6) → 1-(2,2,2-Trichloroethyl)-2-(iodomethyl)-3,4,5,6-tetramethylbenzene (76036-49-2)

Guidance literature:

With sodium iodide; In acetone; for 1h; Heating;

DOI:10.1021/jo00320a025

Reference yield: 58.0%

1-Bromomethyl-2,3,4,5-tetramethyl-6-(2,2,2-trichloro-ethyl)-benzene (70130-76-6) → 1-(2,2,2-Trichloroethyl)-2-(fluoromethyl)-3,4,5,6-tetramethylbenzene (76036-50-5)

Guidance literature:

With silver fluoride; In acetonitrile; for 1h; Ambient temperature;

DOI:10.1021/jo00320a025

upstream raw materials:

Bromotrichloromethane

1,2,5,6-Tetramethyl-3,4-dimethylenetricyclo<3.1.0.0(2,6)>hexan

Downstream raw materials:

1-(2,2,2-Trichloroethyl)-2-(fluoromethyl)-3,4,5,6-tetramethylbenzene

1-(2,2,2-Trichloroethyl)-2-(iodomethyl)-3,4,5,6-tetramethylbenzene