(Z)-7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-hept-5-enoic acid methyl ester

Base Information

• Chemical Name: (Z)-7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-hept-5-enoic acid methyl ester
• CAS No.: 890844-53-8
• Molecular Formula: C₂₆H₃₆O₅
• Molecular Weight: 428.569

Synonyms:(Z)-7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-hept-5-enoic acid methyl ester

Chemical Property of (Z)-7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-hept-5-enoic acid methyl ester

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Technology Process of (Z)-7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-hept-5-enoic acid methyl ester

There total 1 articles about (Z)-7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-hept-5-enoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(Z)-7-((1R,2S,3R)-3-(tert-butyl-dimethyl-silanyloxy)-2-{4-[(tert-butyl-dimethyl-silanyloxy)-cyclohexyl-methyl]-phenyl}-5-oxo-cyclopentyl)-hept-5-enoic acid methyl ester (890844-52-7) → (Z)-7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-hept-5-enoic acid methyl ester (890844-53-8)

Guidance literature:

With pyridine hydrogenfluoride; In acetonitrile; at 0 ℃; for 1h;

Reference yield: 80.0%

(Z)-7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-hept-5-enoic acid methyl ester (890844-53-8) → (Z)-7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-hept-5-enoic acid

Guidance literature:

With water; Rabbit liver esterase; In acetonitrile; pH=7.2; Enzymatic reaction; phosphate buffer;

Reference yield: 22.0%

(Z)-7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-hept-5-enoic acid methyl ester (890844-53-8) → 7-{(1R,2S,3R)-2-[4-(cyclohexyl-hydroxy-methyl)-phenyl]-3-hydroxy-5-oxo-cyclopentyl}-heptanoic acid methyl ester

Guidance literature:

With hydrogen; 5% palladium over charcoal; In methanol; for 4h; under 760.051 Torr;

upstream raw materials:

(Z)-7-((1R,2S,3R)-3-(tert-butyl-dimethyl-silanyloxy)-2-{4-[(tert-butyl-dimethyl-silanyloxy)-cyclohexyl-methyl]-phenyl}-5-oxo-cyclopentyl)-hept-5-enoic acid methyl ester

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