ferricenium tetrakis(pentafluorophenyl)borate

Base Information

• Chemical Name: ferricenium tetrakis(pentafluorophenyl)borate
• CAS No.: 135348-57-1
• Molecular Formula: C₁₀H₁₀Fe*C₂₄BF₂₀
• Molecular Weight: 865.079
• Mol file: 135348-57-1.mol

Synonyms:ferricenium tetrakis(pentafluorophenyl)borate

Chemical Property of ferricenium tetrakis(pentafluorophenyl)borate

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ferricenium tetrakis(pentafluorophenyl)borate

There total 4 articles about ferricenium tetrakis(pentafluorophenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

ferrocenium chloride + potassium tetrakis(pentafluorophenyl)borate → ferricenium tetrakis(pentafluorophenyl)borate (135348-57-1)

Guidance literature:

In dichloromethane; at 20 ℃; for 5h; Reagent/catalyst;

DOI:10.1021/acs.inorgchem.5b01395

Reference yield: 88.26%

ferrocene (102-54-5,55404-68-7) + tetrakis(acetonitrile)silver(I) tetrakis(pentafluorophenyl)borate (848737-65-5) → ferricenium tetrakis(pentafluorophenyl)borate (135348-57-1)

Guidance literature:

In 2-methyltetrahydrofuran; at 20 ℃; for 1h; Glovebox; Inert atmosphere; Darkness;

DOI:10.1039/d1dt01192h

Reference yield: 70.0%

ferrocene (102-54-5,55404-68-7) + lithium tetrakis(pentafluorophenyl)borate ethyl etherate (538369-97-0) → ferricenium tetrakis(pentafluorophenyl)borate (135348-57-1)

Guidance literature:

ferrocene; With iron(III) chloride; In water; acetone; for 0.333333h; Inert atmosphere; Schlenk technique; Glovebox;

lithium tetrakis(pentafluorophenyl)borate ethyl etherate; In water; acetone; for 0.25h; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1039/c5dt00105f

upstream raw materials:

ferrocene

lithium tetrakis(pentafluorophenyl)borate ethyl etherate

tetrakis(acetonitrile)silver(I) tetrakis(pentafluorophenyl)borate

Downstream raw materials:

ferrocene

Refernces

• 1、 Nafady, Ayman,Chin, Teen T.,Geiger, William E.. "Manipulating the electrolyte medium to favor either one-electron or two-electron oxidation pathways for (fulvalendiyl)dirhodium complexes". . p. 1654 - 1663. Retrieved 2006.
• 2、 Spinney, Heather A.,Clough, Christopher R.,Cummins, Christopher C.. "The titanium tris-anilide cation [Ti(N[tBu]Ar)3]+ stabilized as its perfluoro-tetra-phenylborate salt: Structural characterization and synthesis in connection with redox activity of 4,4′-bipyridine dititanium complexes". . p. 6784 - 6796. Retrieved 2015/04/14.