bis(2-phenethyl)phosphinodiselenoic acid potassium salt

Base Information

• Chemical Name: bis(2-phenethyl)phosphinodiselenoic acid potassium salt
• CAS No.: 1201799-79-2
• Molecular Formula: C₁₆H₁₈PSe₂*K
• Molecular Weight: 438.311
• Mol file: 1201799-79-2.mol

Synonyms:bis(2-phenethyl)phosphinodiselenoic acid potassium salt

Chemical Property of bis(2-phenethyl)phosphinodiselenoic acid potassium salt

Chemical Property:

Purity/Quality:

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Technology Process of bis(2-phenethyl)phosphinodiselenoic acid potassium salt

There total 3 articles about bis(2-phenethyl)phosphinodiselenoic acid potassium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

bis(2-phenylethyl)phosphine selenide (923023-81-8) → bis(2-phenethyl)phosphinodiselenoic acid potassium salt (1201799-79-2)

Guidance literature:

With selenium; potassium hydroxide; In tetrahydrofuran; ethanol; at 20 - 25 ℃; for 0.00694444h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2009.03.010

Reference yield: 95.0%

bis(2-phenethyl)phosphine (93017-30-2) → bis(2-phenethyl)phosphinodiselenoic acid potassium salt (1201799-79-2)

Guidance literature:

With selenium; potassium hydroxide semihydrate; In ethanol; at 20 ℃; for 0.0833333h; Inert atmosphere;

DOI:10.1055/s-0029-1218786

Reference yield: 87.0%

bis(2-phenylethyl)phosphine selenide (923023-81-8) → bis(2-phenethyl)phosphinodiselenoic acid potassium salt (1201799-79-2) + bis(2-phenethyl)phosphine (93017-30-2)

Guidance literature:

With potassium hydroxide; In diethyl ether; ethanol; at 20 ℃; Inert atmosphere;

DOI:10.1134/S0012500809090067

upstream raw materials:

bis(2-phenylethyl)phosphine selenide

bis(2-phenethyl)phosphine

Downstream raw materials:

C₃₂H₃₆Au₂P₂Se₄

bis[di(2-phenylethyl)selenophosphoryl]selenide

bis[di(2-phenethyl)selenophosphoryl]triselenide

Se-prop-2-enyl bis(2-phenylethyl)diselenophosphinate

Refernces

• 1、 Artemev, Alexander V.,Malysheva, Svetlana F.,Gusarova, Nina K.,Trofimov, Boris A.. "Rapid and convenient one-pot method for the preparation of alkali metal phosphinodiselenoates". experimental part. p. 2463 - 2467. Retrieved 2010/09/06.