1,2,3-Triphenylbenzene

Base Information

• Chemical Name: 1,2,3-Triphenylbenzene
• CAS No.: 1165-14-6
• Molecular Formula: C24H18
• Molecular Weight: 306.407
• Hs Code.: 2902909090
• European Community (EC) Number: 251-175-7
• NSC Number: 167324
• DSSTox Substance ID: DTXSID00186393
• Nikkaji Number: J7.293A
• Wikidata: Q83057666
• Mol file: 1165-14-6.mol

Synonyms:1,2,3-Triphenylbenzene;1165-14-6;ar'-Phenylterphenyl;m-Terphenyl, 2'-phenyl-;32718-86-8;o-Terphenyl, 3'-phenyl-;1,1'-Biphenyl, 2,3-diphenyl-;EINECS 251-175-7;NSC167324;1,3-Triphenylbenzene;Biphenyl,3-diphenyl-;1,1':2',1''-Terphenyl, 3'-phenyl-;Benzene,2,3-triphenyl-;Biphenyl, 2,3-diphenyl-;Benzene, 1,2,3-triphenyl-;1,2,3-Triphenylbenzene, 97%;DTXSID00186393;CHBDXRNMDNRJJC-UHFFFAOYSA-N;1,1''-Terphenyl, 3'-phenyl-;AKOS015889179;NSC-167324;FT-0759150;J-003451

Chemical Property of 1,2,3-Triphenylbenzene

Chemical Property:

• Vapor Pressure: 2.27E-06mmHg at 25°C
• Melting Point: 157-159 °C(lit.)
• Boiling Point: 404.1°Cat760mmHg
• Flash Point: 195°C
• PSA: 0.00000
• Density: 1.074g/cm³
• LogP: 6.68760
• XLogP3: 7.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 306.140850574
• Heavy Atom Count: 24
• Complexity: 328

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,2,3-Triphenylbenzene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C(C(=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4
• Uses: 2''-Phenyl-m-terphenyl can be used as a multi-layer type electrophotographic photosensitive member.

Technology Process of 1,2,3-Triphenylbenzene

There total 30 articles about 1,2,3-Triphenylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,2,3-trichlorobenzene (87-61-6) + phenylboronic acid (98-80-6) → 1,2,3-triphenylbenzene (1165-14-6)

Guidance literature:

With potassium phosphate; palladium diacetate; DavePhos; In toluene; at 90 ℃; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.mencom.2021.04.039

Reference yield: 94.0%

1,2,3-triphenyl-1,4-cyclohexadien → 1,2,3-triphenylbenzene (1165-14-6)

Guidance literature:

With palladium 10% on activated carbon; acrylic acid; In water; at 120 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c7gc03819d

Reference yield: 92.0%

terphenyl bromide + phenylboronic acid (98-80-6) → 1,2,3-triphenylbenzene (1165-14-6)

Guidance literature:

With sodium hydroxide; In N,N-dimethyl-formamide; at 130 ℃; for 0.216667h; Catalytic behavior; Schlenk technique;

DOI:10.1002/aoc.6266

upstream raw materials:

3,4,5-triphenyl-cyclohex-2-en-1-one

1,7,8-triphenyl-bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid-2,3;5,6-dianhydride

2,3,4-Triphenyl-cyclohexen-1

2,6-di-iodobiphenyl

Downstream raw materials:

1,3,5-triphenylbenzene

1,2,4-triphenylbenzene