K{18-crown-6}{closo-3-(triphenylphosphine)-3-(carbonyl)-3,1,2-RhC₂B₉H₁₁}

Base Information

Chemical Name:K{18-crown-6}{closo-3-(triphenylphosphine)-3-(carbonyl)-3,1,2-RhC₂B₉H₁₁}
CAS No.:85369-56-8
Molecular Formula:C₁₂H₂₄O₆*C₂₁H₂₆B₉OPRh*K
Molecular Weight:829.032
Hs Code.:

K{18-crown-6}{closo-3-(triphenylphosphine)-3-(carbonyl)-3,1,2-RhC<sub>2</sub>B<sub>9</sub>H<sub>11</sub>}

Synonyms:K{18-crown-6}{closo-3-(triphenylphosphine)-3-(carbonyl)-3,1,2-RhC₂B₉H₁₁}

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Chemical Property of K{18-crown-6}{closo-3-(triphenylphosphine)-3-(carbonyl)-3,1,2-RhC₂B₉H₁₁}

Chemical Property:

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Technology Process of K{18-crown-6}{closo-3-(triphenylphosphine)-3-(carbonyl)-3,1,2-RhC₂B₉H₁₁}

There total 2 articles about K{18-crown-6}{closo-3-(triphenylphosphine)-3-(carbonyl)-3,1,2-RhC₂B₉H₁₁} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 85369-62-6
K{18-crown-6}{closo-3-(triphenylphosphine)-3-(eta.2-C(m-FC₆H₄)NOC(O)-)-3,1,2-RhC₂B₉H₁₁}

: 85369-56-8
K{18-crown-6}{closo-3-(triphenylphosphine)-3-(carbonyl)-3,1,2-RhC₂B₉H₁₁}

: 403-54-3
m-Fluorobenzonitrile

Guidance literature:: With CO; In acetone; byproducts: CO2; 40°C, under CO (1 atm).;
DOI:10.1021/om00093a012

Reference yield:

: 85369-62-6
K{18-crown-6}{closo-3-(triphenylphosphine)-3-(eta.2-C(m-FC₆H₄)NOC(O)-)-3,1,2-RhC₂B₉H₁₁}

: 85369-56-8
K{18-crown-6}{closo-3-(triphenylphosphine)-3-(carbonyl)-3,1,2-RhC₂B₉H₁₁}

Guidance literature:: With carbon monoxide; In acetone; at 40°C;
DOI:10.1021/ja00348a087

Reference yield: 79.0%

: 85369-56-8
{K(C₂H₄O)6}⁽¹⁺⁾*{(P(C₆H₅)3)(CO)RhC₂B₉H₁₁}^(1-)={K(C₂H₄O)6}{(P(C₆H₅)3)(CO)RhC₂B₉H₁₁}

: {(P(C₆H₅)3)(CO)(COCH₃)RhC₂B₉H₁₁}

Guidance literature:: With CO; CH₃I; In methanol; addn. of CH3I to suspension of complex under CO, reaction for 6 h; dried, recrystd. (CH2Cl2/MeOH, under CO); elem. anal.;