(S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene

Base Information

Chemical Name:(S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene
CAS No.:1346661-60-6
Molecular Formula:C₂₈H₄₃IO₂Si₂
Molecular Weight:594.724
Hs Code.:

Synonyms:(S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene

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Chemical Property of (S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene

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Technology Process of (S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene

There total 1 articles about (S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: C₂₈H₄₂O₂Si₂

: 1346661-60-6
(S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene

Guidance literature:: C₂₈H₄₂O₂Si₂; With Schwartz's reagent; In tetrahydrofuran; for 1.5h; Inert atmosphere; Darkness;

With iodine; In tetrahydrofuran; at 0 ℃; for 0.166667h; Inert atmosphere;
DOI:10.1021/jo202119p

Reference yield: 93.0%

: 1346661-72-0
C₁₉H₂₆INO₂

: 1346661-60-6
(S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene

: 1346661-74-2
(4R,5R,E)-5-(benzyloxy)-N-((S,2E,4E)-8-(tert-butyldimethylsilyloxy)-6-(tert-butyldiphenylsilyloxy)-4-methylocta-2,4-dienyl)-4,6-dimethylhept-2-enamide

Guidance literature:: (S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 0.5h; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; diethyl ether; pentane; at -78 ℃; for 0.333333h; Inert atmosphere;

C₁₉H₂₆INO₂; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; pentane; regioselective reaction; Inert atmosphere;
DOI:10.1021/jo202119p

Reference yield: 92.0%

: 1346661-73-1
(3R,4R,E)-7-((E)-3-iodoallylamino)-2,4-dimethyl-7-oxohept-5-en-3-yl acetate

: 1346661-60-6
(S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene

: 1346661-76-4
(3R,4R,E)-7-((S,2E,4E)-8-(tert-butyldimethylsilyloxy)-6-(tertbutyldiphenylsilyloxy)-4-methylocta-2,4-dienylamino)-2,4-dimethyl-7-oxohept-5-en-3-yl acetate

Guidance literature:: (S,E)-1-(tert-butyl(1-(tert-butyldimethylsilyloxy)-5-iodohex-4-en-3-yloxy)(phenyl)silyl)benzene; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 0.5h; Inert atmosphere;

With zinc(II) chloride; In tetrahydrofuran; diethyl ether; pentane; at -78 ℃; for 0.333333h; Inert atmosphere;

(3R,4R,E)-7-((E)-3-iodoallylamino)-2,4-dimethyl-7-oxohept-5-en-3-yl acetate; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; diethyl ether; pentane; regioselective reaction; Inert atmosphere;
DOI:10.1021/jo202119p