NO₂C₆H₄COPdI(P(C₆H₅)3)2

Base Information

• Chemical Name: NO₂C₆H₄COPdI(P(C₆H₅)3)2
• CAS No.: 99639-35-7
• Molecular Formula: C₄₃H₃₄INO₃P₂Pd
• Molecular Weight: 908.02
• Mol file: 99639-35-7.mol

Synonyms:NO₂C₆H₄COPdI(P(C₆H₅)3)2

Chemical Property of NO₂C₆H₄COPdI(P(C₆H₅)3)2

Chemical Property:

Purity/Quality:

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Technology Process of NO₂C₆H₄COPdI(P(C₆H₅)3)2

There total 1 articles about NO₂C₆H₄COPdI(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(4-nitrophenyl)Pd(P(C6H5)3)2I (33377-47-8,67254-08-4) → NO2C6H4COPdI(P(C6H5)3)2 (99639-35-7)

Guidance literature:

With carbon monoxide; In N,N,N,N,N,N-hexamethylphosphoric triamide; 1 atm CO, 20 °C, 5 h;

DOI:10.1016/0022-328X(85)87385-X

Reference yield: 67.0%

(Et)3tin(phenylthiolate) (1012-56-2) + NO2C6H4COPdI(P(C6H5)3)2 (99639-35-7) → S-phenyl 4-nitrobenzothioate (3128-43-6)

Guidance literature:

In N,N,N,N,N,N-hexamethylphosphoric triamide; at 20 ℃; for 0.5h;

DOI:10.1016/0022-328X(85)87385-X

Reference yield: 60.0%

triethylmethoxystannane (1067-21-6) + NO2C6H4COPdI(P(C6H5)3)2 (99639-35-7) → 4-nitrobenzoic acid methyl ester (619-50-1)

Guidance literature:

In N,N,N,N,N,N-hexamethylphosphoric triamide; at 20 ℃; for 2h;

DOI:10.1016/0022-328X(85)87385-X

upstream raw materials:

(4-nitrophenyl)Pd(P(C₆H₅)3)2I

Downstream raw materials:

S-phenyl 4-nitrobenzothioate

4-nitrobenzoic acid methyl ester

Refernces