(R)-2-Benzyloxymethyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol

Base Information

Chemical Name:(R)-2-Benzyloxymethyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol
CAS No.:130114-58-8
Molecular Formula:C₁₆H₂₂O₄
Molecular Weight:278.348
Hs Code.:

Synonyms:(R)-2-Benzyloxymethyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol

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Chemical Property of (R)-2-Benzyloxymethyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol

Chemical Property:

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Technology Process of (R)-2-Benzyloxymethyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol

There total 7 articles about (R)-2-Benzyloxymethyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 130114-57-7
(2S,3R)-5-benzyl-2,3-O-isopropylidene-4-C-methylene-D-erytho-pentitol

: 130114-58-8
(R)-2-Benzyloxymethyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol

Guidance literature:: With amberlyst-15; In acetone; for 12h; Yield given; Ambient temperature;
DOI:10.1016/0040-4039(90)80222-8

Reference yield:

: 2042-27-5
L-ribulose

: 130114-58-8
(R)-2-Benzyloxymethyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol

Guidance literature:: Multi-step reaction with 6 steps

1: 94 percent / pTSA / 24 h / Ambient temperature

2: 92 percent / KOtBu / tetrahydrofuran / 2 h / Ambient temperature

3: 100 percent / 10percent HCl / tetrahydrofuran / 4 h / Ambient temperature

4: 80 percent / pTSA / 0.5 h / Ambient temperature

5: 84 percent / 12-crown-4 / tetrahydrofuran / 4 h / -60 deg C to r.t.

6: Amberlyst-15 / acetone / 12 h / Ambient temperature

With hydrogenchloride; amberlyst-15; (1,4,7,10-tetraoxacyclododecane); potassium tert-butylate; toluene-4-sulfonic acid; In tetrahydrofuran; acetone;
DOI:10.1016/0040-4039(90)80222-8

Reference yield:

: 130114-49-7,130114-50-0
((3aS,4S,6aS)-2,4-Dimethoxy-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-methanol

: 130114-58-8
(R)-2-Benzyloxymethyl-1-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-prop-2-en-1-ol

Guidance literature:: Multi-step reaction with 5 steps

1: 92 percent / KOtBu / tetrahydrofuran / 2 h / Ambient temperature

2: 100 percent / 10percent HCl / tetrahydrofuran / 4 h / Ambient temperature

3: 80 percent / pTSA / 0.5 h / Ambient temperature

4: 84 percent / 12-crown-4 / tetrahydrofuran / 4 h / -60 deg C to r.t.

5: Amberlyst-15 / acetone / 12 h / Ambient temperature

With hydrogenchloride; amberlyst-15; (1,4,7,10-tetraoxacyclododecane); potassium tert-butylate; toluene-4-sulfonic acid; In tetrahydrofuran; acetone;
DOI:10.1016/0040-4039(90)80222-8