Technology Process of C48H57N3O8Si
There total 5 articles about C48H57N3O8Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C49H59N3O8Si;
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at -10 ℃;
for 0.416667h;
With
TEA;
In
dichloromethane;
at -10 - 0 ℃;
With
trifluoroacetic anhydride;
In
dichloromethane;
at 0 ℃;
for 0.5h;
DOI:10.1021/jo034547i
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: 87 percent / imidazole; DMAP / dimethylformamide / 1.25 h / 23 °C
2.1: 100 percent / NaH / tetrahydrofuran; H2O / 1 h / 0 °C
3.1: m-CPBA / CH2Cl2 / 0.42 h / -10 °C
3.2: TEA / CH2Cl2 / -10 - 0 °C
3.3: 85 percent / TFAA / CH2Cl2 / 0.5 h / 0 °C
With
1H-imidazole; dmap; sodium hydride; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jo034547i
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: 50 percent / NaNO2; aq. KH2PO4; H3PO4 / CH2Cl2 / 48 h / 23 °C
2.1: 87 percent / imidazole; DMAP / dimethylformamide / 1.25 h / 23 °C
3.1: 100 percent / NaH / tetrahydrofuran; H2O / 1 h / 0 °C
4.1: m-CPBA / CH2Cl2 / 0.42 h / -10 °C
4.2: TEA / CH2Cl2 / -10 - 0 °C
4.3: 85 percent / TFAA / CH2Cl2 / 0.5 h / 0 °C
With
1H-imidazole; dmap; potassium dihydrogenphosphate; phosphoric acid; sodium hydride; 3-chloro-benzenecarboperoxoic acid; sodium nitrite;
In
tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jo034547i
