benzyl (1S,2S)-2-methoxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethylcarbamate

Base Information

Chemical Name:benzyl (1S,2S)-2-methoxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethylcarbamate
CAS No.:874894-80-1
Molecular Formula:C₂₃H₂₇NO₆
Molecular Weight:413.47
Hs Code.:

Synonyms:benzyl (1S,2S)-2-methoxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethylcarbamate

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Chemical Property of benzyl (1S,2S)-2-methoxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethylcarbamate

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Technology Process of benzyl (1S,2S)-2-methoxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethylcarbamate

There total 1 articles about benzyl (1S,2S)-2-methoxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 420-37-1
trimethoxonium tetrafluoroborate

: 874894-79-8
(1S,2S)-benzyl 2-hydroxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethylcarbamate

: 874894-80-1
benzyl (1S,2S)-2-methoxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethylcarbamate

Guidance literature:: With N,N,N',N'-tetramethyl-1,8-diaminonaphthalene; In dichloromethane; at 20 ℃; for 8h;
DOI:10.1016/j.tetasy.2005.10.029

Reference yield: 86.0%

: 874894-80-1
benzyl (1S,2S)-2-methoxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethylcarbamate

: (1S,2S)-2-methoxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethanamine

Guidance literature:: With hydrogen; palladium dihydroxide; In ethanol; ethyl acetate; under 2327.17 Torr;
DOI:10.1016/j.tetasy.2005.10.029

Reference yield:

: 874894-80-1
benzyl (1S,2S)-2-methoxy-1-(4'-methyl-2',6',7'-trioxabicyclo[2.2.2]-octan-1'-yl)-2-phenylethylcarbamate

: (2S,3S)-2-amino-3-methoxy-3-phenylpropanoic acid

Guidance literature:: Multi-step reaction with 2 steps

1.1: 86 percent / hydrogen / Pd(OH)2/C / ethyl acetate; ethanol / 2327.17 Torr

2.1: trifluoroacetic acid / H₂O / 45 h / 20 °C

2.2: 72 percent / Cs₂CO₃ / H₂O / 16 h

With hydrogen; trifluoroacetic acid; palladium dihydroxide; In ethanol; water; ethyl acetate;
DOI:10.1016/j.tetasy.2005.10.029