(1S,2R,5S,6R)-2-(benzoyloxy)-5,6-dihydroxy-4-iodo-3-cyclohexenyl benzoate

Base Information

Chemical Name:(1S,2R,5S,6R)-2-(benzoyloxy)-5,6-dihydroxy-4-iodo-3-cyclohexenyl benzoate
CAS No.:856890-07-8
Molecular Formula:C₂₀H₁₇IO₆
Molecular Weight:480.256
Hs Code.:

Synonyms:(1S,2R,5S,6R)-2-(benzoyloxy)-5,6-dihydroxy-4-iodo-3-cyclohexenyl benzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1S,2R,5S,6R)-2-(benzoyloxy)-5,6-dihydroxy-4-iodo-3-cyclohexenyl benzoate

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Technology Process of (1S,2R,5S,6R)-2-(benzoyloxy)-5,6-dihydroxy-4-iodo-3-cyclohexenyl benzoate

There total 4 articles about (1S,2R,5S,6R)-2-(benzoyloxy)-5,6-dihydroxy-4-iodo-3-cyclohexenyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 856890-00-1
(3aR,4S,5R,7aS)-5-(benzoyloxy)-7-iodo-2,2-dimethyl-3a,4,5,7a-tetrahydro-1,3-benzodioxol-5-yl benzoate

: 856890-07-8
(1S,2R,5S,6R)-2-(benzoyloxy)-5,6-dihydroxy-4-iodo-3-cyclohexenyl benzoate

Guidance literature:: With hydrogenchloride; In methanol; at 50 ℃; for 4h;
DOI:10.1039/b502009c

Reference yield:

: 138769-92-3
cis-(1S,2S)-1,2-dihydroxy-3-iodocyclohexa-3,5-diene

: 856890-07-8
(1S,2R,5S,6R)-2-(benzoyloxy)-5,6-dihydroxy-4-iodo-3-cyclohexenyl benzoate

Guidance literature:: Multi-step reaction with 4 steps

1: 98 percent / p-toluenesulfonic acid / acetone / 4 h / 0 - 20 °C

2: 87 percent / N-methylmorpholine N-oxide; aq. OsO₄ / acetone / 12 h / 20 °C

3: 95 percent / pyridine / 20 °C

4: 90 percent / aq. HCl / methanol / 4 h / 50 °C

With pyridine; hydrogenchloride; osmium(VIII) oxide; toluene-4-sulfonic acid; 4-methylmorpholine N-oxide; In methanol; acetone;
DOI:10.1039/b502009c

Reference yield:

: 154784-39-1
(3aS,7aS)-4-iodo-2,2-dimethyl-3a,7a-dihydro-1,3-benzodioxole

: 856890-07-8
(1S,2R,5S,6R)-2-(benzoyloxy)-5,6-dihydroxy-4-iodo-3-cyclohexenyl benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / N-methylmorpholine N-oxide; aq. OsO₄ / acetone / 12 h / 20 °C

2: 95 percent / pyridine / 20 °C

3: 90 percent / aq. HCl / methanol / 4 h / 50 °C

With pyridine; hydrogenchloride; osmium(VIII) oxide; 4-methylmorpholine N-oxide; In methanol; acetone;
DOI:10.1039/b502009c