1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzyloxycarbonylamino)-β-D-glucopyranoside

Base Information

Chemical Name:1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzyloxycarbonylamino)-β-D-glucopyranoside
CAS No.:130259-43-7
Molecular Formula:C₂₃H₃₀N₂O₁₂
Molecular Weight:526.497
Hs Code.:

Synonyms:1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzyloxycarbonylamino)-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzyloxycarbonylamino)-β-D-glucopyranoside

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Technology Process of 1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzyloxycarbonylamino)-β-D-glucopyranoside

There total 5 articles about 1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzyloxycarbonylamino)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 130259-34-6
1,3,4,6-tetra-O-acetyl-2-deoxy-2-(4-nitrobenzyloxycarbonylamino)-β-D-glucopyranose

: 67-63-0,8013-70-5
isopropyl alcohol

: 130259-43-7
1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzyloxycarbonylamino)-β-D-glucopyranoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -35 ℃;
DOI:10.1016/0008-6215(90)84077-8

Reference yield: 2.0%

: 130259-38-0
Acetic acid (2R,3S,4R,5R,6R)-3-acetoxy-2-acetoxymethyl-6-bromo-5-(4-nitro-benzyloxycarbonylamino)-tetrahydro-pyran-4-yl ester

: 67-63-0,8013-70-5
isopropyl alcohol

: 130259-43-7
1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzyloxycarbonylamino)-β-D-glucopyranoside

: 76548-23-7,10163-09-4
tetrahydro-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranoso)[2,1-d]-1,3-oxazol-2-one

Guidance literature:: With mercury(II) cyanide; In dichloromethane; Ambient temperature;
DOI:10.1016/0008-6215(90)84077-8

Reference yield:

: 7597-81-1,34948-61-3,55628-19-8,74554-00-0,103382-86-1,114297-26-6
(2S,3R,4R,5S,6R)-6-(acetoxymethyl)-3-((E)-(4-methoxybenzylidene)amino)tetrahydro-2Hpyran-2,4,5-triyl triacetate

: 130259-43-7
1-methylethyl 3,4,6-tri-O-acetyl-2-deoxy-2-(4-nitrobenzyloxycarbonylamino)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 5.5 M HCl / acetone / Heating

2: 1. NaHCO₃ / 1. H₂O 2. CHCl₃, 1 h, room temperature

3: 33percent HBr / acetic acid / 3 h / Ambient temperature

4: 63 percent / Hg(CN)2 / CH₂Cl₂ / Ambient temperature

With hydrogenchloride; hydrogen bromide; mercury(II) cyanide; sodium hydrogencarbonate; In dichloromethane; acetic acid; acetone;
DOI:10.1016/0008-6215(90)84077-8