[(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(-1H))RuCl(PPh₃)(DMSO)]

Base Information

• Chemical Name: [(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(-1H))RuCl(PPh₃)(DMSO)]
• CAS No.: 1035383-10-8
• Molecular Formula: C₃₇H₃₅ClN₅OPRuS
• Molecular Weight: 765.281

Synonyms:[(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(-1H))RuCl(PPh₃)(DMSO)]

Chemical Property of [(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(-1H))RuCl(PPh₃)(DMSO)]

Chemical Property:

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Technology Process of [(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(-1H))RuCl(PPh₃)(DMSO)]

There total 2 articles about [(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(-1H))RuCl(PPh₃)(DMSO)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

[(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine)RuCl(PPh3)(DMSO)]Cl → [(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(-1H))RuCl(PPh3)(DMSO)] (1035383-10-8)

Guidance literature:

With NaHCO₃; In methanol; dichloromethane; mixt. of Ru complex and NaHCO3 in CH2Cl2/MeOH was stirred at ambient temp. for 15 h; filtered through Celite; evapd. (vac.);

DOI:10.1021/om801080p

Reference yield:

[(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(-1H))RuCl(PPh3)2] (1134285-03-2) + dimethyl sulfoxide (67-68-5,8070-53-9) → [(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(-1H))RuCl(PPh3)(DMSO)] (1035383-10-8)

Guidance literature:

In chloroform-d1; soln. of Ru complex in CDCl3 was treated with DMSO; NMR monitoring;

DOI:10.1021/om801080p

upstream raw materials:

[(2-(benzoimidazol-2-yl)-6-(3,5-dimethylpyrazol-1-yl)pyridine(-1H))RuCl(PPh₃)2]

dimethyl sulfoxide

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