methyl 1,6-bis-O-(triphenylmethyl)-2,3-dideoxy-2,3-didehydro-α-D-fructofuranoside

Base Information

Chemical Name:methyl 1,6-bis-O-(triphenylmethyl)-2,3-dideoxy-2,3-didehydro-α-D-fructofuranoside
CAS No.:128804-02-4
Molecular Formula:C₄₅H₄₀O₄
Molecular Weight:644.81
Hs Code.:

Synonyms:methyl 1,6-bis-O-(triphenylmethyl)-2,3-dideoxy-2,3-didehydro-α-D-fructofuranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 1,6-bis-O-(triphenylmethyl)-2,3-dideoxy-2,3-didehydro-α-D-fructofuranoside

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Technology Process of methyl 1,6-bis-O-(triphenylmethyl)-2,3-dideoxy-2,3-didehydro-α-D-fructofuranoside

There total 2 articles about methyl 1,6-bis-O-(triphenylmethyl)-2,3-dideoxy-2,3-didehydro-α-D-fructofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 128804-01-3
methyl 2,3-anhydro-1,6-bis-O-(triphenylmethyl)-α-D-lyxo-hexulofuranoside

: 128804-02-4
methyl 1,6-bis-O-(triphenylmethyl)-2,3-dideoxy-2,3-didehydro-α-D-fructofuranoside

Guidance literature:: With bis(cyclopentadienyl)titanium (III) chloride;
DOI:10.1021/ja00173a045

Reference yield:

: 128804-06-8
methyl 1,6-bis-O-(triphenylmethyl)-α-D-fructofuranoside

: 128804-02-4
methyl 1,6-bis-O-(triphenylmethyl)-2,3-dideoxy-2,3-didehydro-α-D-fructofuranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / Ph₃P, diethyl azodicarboxylate / tetrahydrofuran / 0.75 h / 80 °C

2: 66 percent / bis(cyclopentadienyl)titanium(III) chloride (Cp₂TiCl) / tetrahydrofuran / 0.33 h

With bis(cyclopentadienyl)titanium (III) chloride; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran;
DOI:10.1021/ja00082a021