methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-acetyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside

Base Information

Chemical Name:methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-acetyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside
CAS No.:666728-58-1
Molecular Formula:C₄₀H₄₈N₂O₁₂
Molecular Weight:748.827
Hs Code.:

Synonyms:methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-acetyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside

Suppliers and Price of methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-acetyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-acetyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-acetyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside

There total 12 articles about methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-acetyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 81927-55-1
O-benzyl 2,2,2-trichloroacetimidate

: 666728-58-1
methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-acetyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 67 percent / 4 Angstroem molecular sieves; CF₃SO₃H / CH₂Cl₂; hexane / 1 h / cooling

2: 72 percent / Bu₄NF / tetrahydrofuran / 4 h / -20 °C

3: DBU / CH₂Cl₂ / 2 h

4: 4 Angstroem molecular sieves; trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / -5 °C

5: NaOH / dioxane; H₂O / 4 h / 20 °C

6: pyridine / 20 °C

With pyridine; sodium hydroxide; trifluorormethanesulfonic acid; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; tetrabutyl ammonium fluoride; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; 1,4-dioxane; hexane; dichloromethane; water;
DOI:10.1021/jo035397e

Reference yield:

: 87038-18-4
methyl 2-acetylamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside

: 666728-58-1
methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-acetyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine / CH₂Cl₂ / 20 °C

2: 4 Angstroem molecular sieves; trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / -5 °C

3: NaOH / dioxane; H₂O / 4 h / 20 °C

4: pyridine / 20 °C

With pyridine; sodium hydroxide; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; In 1,4-dioxane; dichloromethane; water;
DOI:10.1021/jo035397e

Reference yield:

: 10378-06-0,20757-53-3,35954-65-5,123483-77-2,134308-33-1
2-methyl-(3,4,6-tri-O-acetyl-1,2-dideoxy-α-D-glucopyranoso)[1,2-d]-2-oxazoline

: 666728-58-1
methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-β-D-glucopyranosyl-(1->4)-2-acetamido-3-O-acetyl-6-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 7 steps

1: 95 percent / BF₃*Et₂O / methanol / 20 °C

2: NaOMe / methanol / 0.5 h / 20 °C

3: p-toluenesulfonic acid monohydrate / acetonitrile / 2 h / 20 °C

4: pyridine / CH₂Cl₂ / 20 °C

5: 4 Angstroem molecular sieves; trimethylsilyl trifluoromethanesulfonate / CH₂Cl₂ / -5 °C

6: NaOH / dioxane; H₂O / 4 h / 20 °C

7: pyridine / 20 °C

With pyridine; sodium hydroxide; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; boron trifluoride diethyl etherate; sodium methylate; toluene-4-sulfonic acid; In 1,4-dioxane; methanol; dichloromethane; water; acetonitrile;
DOI:10.1021/jo035397e