[2-(4-methyl-5-phenyl-2-pyridyl-κN)phenyl-κC]bis[2-(2-pyridyl-κN)phenyl-κC]iridium

Base Information

Chemical Name:[2-(4-methyl-5-phenyl-2-pyridyl-κN)phenyl-κC]bis[2-(2-pyridyl-κN)phenyl-κC]iridium
CAS No.:1215692-34-4
Molecular Formula:C₄₀H₃₀IrN₃
Molecular Weight:744.918
Hs Code.:

Synonyms:[2-(4-methyl-5-phenyl-2-pyridyl-κN)phenyl-κC]bis[2-(2-pyridyl-κN)phenyl-κC]iridium

Suppliers and Price of [2-(4-methyl-5-phenyl-2-pyridyl-κN)phenyl-κC]bis[2-(2-pyridyl-κN)phenyl-κC]iridium

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 5 raw suppliers

Chemical Property of [2-(4-methyl-5-phenyl-2-pyridyl-κN)phenyl-κC]bis[2-(2-pyridyl-κN)phenyl-κC]iridium

Chemical Property:

Purity/Quality:: 95% ^*data from raw suppliers

Safty Information:

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Description Like Ir(ppy)3, [2-(4-methyl-5-phenyl-2-pyridinyl-κN)phenyl-κC]bis[2-(2-pyridinyl-κN)phenyl-κC] Iridium, known as?Ir(ppy)2(bpmp), is a phosphorescent green emitter. It is believed that the introduction of the?methyl group at para position to the pyridine nitrogen can provide a twist and electron-donating effect. This raises the LUMO energy level of the complex and the triplet energy level, resulting in a blue shift in the emission.

Technology Process of [2-(4-methyl-5-phenyl-2-pyridyl-κN)phenyl-κC]bis[2-(2-pyridyl-κN)phenyl-κC]iridium

There total 6 articles about [2-(4-methyl-5-phenyl-2-pyridyl-κN)phenyl-κC]bis[2-(2-pyridyl-κN)phenyl-κC]iridium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1008-89-5
2-phenylpyridine

: 156021-08-8
2,5-diphenyl-4-methylpyridine

: 94928-86-6
tris[2-phenylpyridinato-C₂,N]iridium(III)

: 1215692-67-3
C₄₇H₃₆IrN₃

: 1215692-34-4
[2-(4-methyl-5-phenyl-2-pyridyl-κN)phenyl-κC]bis[2-(2-pyridyl-κN)phenyl-κC]iridium

: Ir(4-methyl-2,5-diphenylpyridine)₃

Guidance literature:: In water; ethylene glycol; at 180 ℃; for 17h; Inert atmosphere;

Reference yield:

: 1215692-14-0
[Ir(phenylpyridine)2(MeOH)2](OTf)

: 156021-08-8
2,5-diphenyl-4-methylpyridine

: 1215692-34-4
[2-(4-methyl-5-phenyl-2-pyridyl-κN)phenyl-κC]bis[2-(2-pyridyl-κN)phenyl-κC]iridium

Guidance literature:: In ethanol; for 24h; Inert atmosphere; Reflux;

Reference yield:

: 98-80-6
phenylboronic acid

: 1215692-34-4
[2-(4-methyl-5-phenyl-2-pyridyl-κN)phenyl-κC]bis[2-(2-pyridyl-κN)phenyl-κC]iridium

Guidance literature:: Multi-step reaction with 2 steps

1: potassium phosphate monohydrate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾ / water; toluene / 16 h / Inert atmosphere; Reflux

2: ethanol / 24 h / Inert atmosphere; Reflux

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium phosphate monohydrate; In ethanol; water; toluene;