Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-formyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

Base Information

Chemical Name:Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-formyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester
CAS No.:123266-80-8
Molecular Formula:C₂₆H₂₉NO₉S
Molecular Weight:531.584
Hs Code.:

Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-formyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

Synonyms:Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-formyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

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Chemical Property of Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-formyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

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Technology Process of Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-formyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

There total 1 articles about Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-formyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 123289-27-0
Acetic acid (1R,2aS,3S,7dR)-4-benzyloxy-2a-ethylsulfanyl-5,7-dimethoxy-6-methyl-3-((Z)-2-phenyl-2-trimethylsilanyloxy-vinyl)-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

: 123266-80-8
Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-formyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

Guidance literature:: With ruthenium(IV) oxide; sodium periodate; In water; ethyl acetate; at 23 ℃;
DOI:10.1021/ja00203a055

Reference yield: 97.0%

: 123266-80-8
Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-formyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

: 123266-81-9
Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-hydroxymethyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

Guidance literature:: With sodium tetrahydroborate; In methanol;
DOI:10.1021/ja00203a055

Reference yield:

: 123266-80-8
Acetic acid (1S,2aR,3S,7dS)-4-benzyloxy-2a-ethanesulfonyl-3-formyl-5,7-dimethoxy-6-methyl-2a,3,7c,7d-tetrahydro-1H-2-oxa-7b-aza-benzo[f]cyclopropa[cd]inden-1-yl ester

: 50-07-7,69515-74-8,102679-62-9,111768-87-7,148091-11-6
(+/-)-Mitomycin C

Guidance literature:: Multi-step reaction with 6 steps

1: 97 percent / NaBH₄ / methanol

2: CH₂Cl₂ / 23 °C

3: 1.) NH₃, 2.) NaBH₄ / 1.) CH₃OH, 23 deg C

4: 60 percent / 1.) camphorsulfonic acid / 23 °C

5: 1.) H₂ (1 atm), 2.) DDQ / 1.) 10percent Pd/C / 1.) ethanol, 2.) acetone, water, -78 deg C

6: 85 percent / NH₃ / methanol / 23 °C

With sodium tetrahydroborate; camphor-10-sulfonic acid; ammonia; hydrogen; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium on activated charcoal; In methanol; dichloromethane;
DOI:10.1021/ja00203a055