pentamethylcyclopentadienylcopper(I) triphenylphosphine

Base Information

Chemical Name:pentamethylcyclopentadienylcopper(I) triphenylphosphine
CAS No.:86024-09-1
Molecular Formula:C₂₈H₃₀CuP
Molecular Weight:461.066
Hs Code.:

Synonyms:pentamethylcyclopentadienylcopper(I) triphenylphosphine

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Chemical Property of pentamethylcyclopentadienylcopper(I) triphenylphosphine

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Technology Process of pentamethylcyclopentadienylcopper(I) triphenylphosphine

There total 5 articles about pentamethylcyclopentadienylcopper(I) triphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 51905-34-1
pentamethylcyclopentadienyllithium

: copper(l) chloride

: 86024-09-1
pentamethylcyclopentadienylcopper(I) triphenylphosphine

Guidance literature:: With triphenylphosphine; In tetrahydrofuran; a suspn. of CuCl was mixed with LiC5Me5 at -78°C, the resulting yellow soln. was quenched with a THF soln. of 1 equiv of Ph3P, mixt. was stirred at 0°C for 2 h; filtered over Na2SO4, crystd. from THF; elem. anal.;

Reference yield: 43.0%

: [(triphenylphosphine)Cu(chloride)]4

: 51905-34-1
pentamethylcyclopentadienyllithium

: 86024-09-1
pentamethylcyclopentadienylcopper(I) triphenylphosphine

Guidance literature:: In tetrahydrofuran; under N2, Li(C5Me5) and complex were cooled to -10°C and THF wasadded to the mixt., mixt. was stirred for 6 h while warming to 25°C; THF was evapd., residue was extracted with Et2O, extracts were filtered, filtrate was concd., cooled to -78°C overnight, recrystd. from Et2O at -78°C; elem. anal.;
DOI:10.1021/ja00354a023

Reference yield: 30.0%

: (ClCuP(C₆H₅)3)2

: 51905-34-1
pentamethylcyclopentadienyllithium

: 86024-09-1
pentamethylcyclopentadienylcopper(I) triphenylphosphine

Guidance literature:: In benzene; an equimol. amt. of (ClCuPPh3)2 was added under N2 to a toluene soln. of LiC5Me5, mixt. was stirred for 1 h at 10°C; evapd. in vacuo, pentane was added, cooled to -78°C, supernatantdecanted, ppt. was suspended in pentane, filtered through Celite, filtrate was concd., cooled to -78°C, crystals were washed with pentane, dried under high vac.; elem. anal.;
DOI:10.1016/S0022-328X(00)99128-9